Questions 26-29 refer to the same strong acid/strong base (SA/SB) titration. Prior to the beginning of the titration, there were 0.0050 moles of HI present in the flask. (Q27) A 25.00 mL solution of 0.200 M hydroiodic acid (HI) is being titrated with 0.200 M sodium hydroxide (NaOH). What is the solution pH when 30.00 mL of titrant have been added?
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- 25.0 cm3 of sodium hydroxide solution is tritrated against 0.2 mol dm–3 hydrochloric acid until the indicator just changes colour. 27.5 cm3 of the acid are required to reach the end point.Phenolphthalein is used as an indicator in the above experiment. What will be its colour change at the end point? From pink to yellow From pink to colourless From yellow to colourless From yellow to pinkA commercial vinegar was analyzed by titration to determine the percent acetic acid. Briefly, 10.00 mL of vinegar sample was diluted to 100. mL solution in volumetric flask. A 25.00 mL aliquot from the diluted vinegar required 25.55 mL of 0.1005 M NaOH to reach the phenolphthalein endpoint. Which is the correct equation between the analyte and titrant reaction? CH3COOH + NaOH → NaCH3COO + H2O 2CH3COOH + NaOH → NaCH3COO + H2O C20H14O4 + NaOH → NaC20H14O4 + H2O CH3COOH + 2NaOH → NaCH3COO + H2O1. What is the molar solubility of PbCl2 in a solution of 0.23 M CaCl2? Ksp = 1.6 ✕ 10-5 for PbCl2. 2. What is the Qsp when 32.0 mL of 6.50 ✕ 10-7 M Na3PO4 are mixed with 41.4 mL of 5.50 ✕ 10-5 M CaCl2? Assume the volumes are additive. Ksp = 2.0 ✕ 10-29. 3. What is the Qsp when 61.0 mL of 1.50 ✕ 10-4 M AgNO3 are mixed with 80.0 mL of 5.20 ✕ 10-3 M CaCl2? Assume the volumes are additive. Ksp = 1.6 ✕ 10-10. 4. What [I-1] is needed to start the precipitation of AgI from a saturated solution of AgCl? Ksp = 2.9 ✕ 10-16 for AgI and Ksp = 1.2 ✕ 10-10 for AgCl.
- Following the monograph procedure, determine the weight in grams of sodium carbonate (MW-106 g/mol) used to standardize a 0.987 N sulfuric acid solution. 1. What specific type of titration is involved? A. Direct Acidemetry B. Direct Alkalimetry C. Residual Acidemetry D. Residual Alkalimetry 2. What is the analyte- titrant chemical reaction involved? A. Strong Base+Weak Acid B. Weak Acid+Strong Base C. Strong Acid+Weak Base D. Weak Base+Strong Acid 3. What is the preferred indicator for the chosen type of reaction above? A. Methyl Orange B. Penolphtalein C. Methyl Red 4. Consider that the burette was completely filled to the 0mp mark before titrating. What is the volume of titrant consumed based from the image below? A. 22.9 mL B. 22.2 mL C. 21.3 mL D. 22.7 mL 5. What is the unknown weight (grams) the problem? Your Answer:A solution containing Mg2+ was buffered to pH 9.81 and titrated with EDTA. Eriochrome black T, with p?a1 = 6.3 and p?a2 = 11.6 was used as the indicator. It is a diprotic acid, H2E What is the fraction of the predominant form of eriochrome black T in solution at this pH? (To answer this, report the alpha fraction of the indicator’s most prevalent species at this pH)Calculate the gravimetric factor of the following. 2 Fe3O4 is sought(Analyte), 3 Fe2O3 is weighed (Precipitate) 2 Fe is sought(Analyte), 1Fe2O3 is weighed (Precipitate)
- For the synthesis of maroon dye, Taylor needs to use a primary amine with a pH between 3.00 and 4.00 for optimum yield. In one of her trials, she dissolved 8.22 g of anilinium chloride, C6H5NH3Cl (MM = 129.58 g/mol) in distilled water to make 250.0 mL solution. Given that Kb of aniline (C6H5NH2) is 4.29 x 10-10, calculate the pH of the salt solution. Yes or No. Will Taylor obtain high yield of maroon using C6H5NH3Cl?'A commercial vinegar was analyzed by titration to determine the percent acetic acid. Briefly, 10.00 mL of vinegar sample was diluted to 100. mL solution in a volumetric flask. A 25.00 mL aliquot from the diluted vinegar required 25.55 mL of 0.1005 M sodium hydroxide to reach the phenolphthalein endpoint From this experiment which is the standard solution used in titration? CH3COOH NaOH NaCH3COO C20H14O4Molarity of titrant (NaOH): 0.4550 M HC2H3O2 (aq) + NaOH (aq) → NaC2H3O2 (aq) + H2O (l) Trial # First Second Third Fourth Initial buret reading 0.15 mL 2.43 mL 1.32 mL 0.58 mL Final buret reading 18.62 mL 20.87 mL 20.03 mL 19.14 mL Volume of titrant used 18.47 mL 18.44 mL 18.71 mL 18.56 mL 4) Calculate the molarity of the acetic acid in the vinegar solution (Show your work). use FW for moles-->grams acetic acid. Molarity acetic acid = _____________ M 5) Calculate the weight % of acetic acid in the vinegar. How does this compare with the % listed on the label (5.00%)? (For this calculation assume that density of vinegar is 1.03 g/mL and of course, show your work). Weight % = ___________ 6) If you didn’t get the same weight % of acetic acid as listed on the vinegar label (5.00 %), what are two things (be specific) that could’ve happened during the experiment that could explain the variation from the expected weight %? To do…
- You have performed an iodimetric titration using a commercial vitamin C tablet. Based on the following information below, calculate the %(w/w) of vitamin C(MM=176.16 g/mol) in the tablet: Mass of tablet dissolved in 250.0 mL: 5.422 g Aliquot volume of sample titrated: 25.00 mL Concentration of KIO3: 0.023 M Final burrette volume: 41.31 mL Initial burrette volume: 8.89 mL Blank volume: 0.14 mLAt the half-way point in the titration of a weak acid with a strong base the pH was measured as 5.16. What is the acidity constant and the pKa of the acid? What is the pH of the solution that is 0.025 M in the acid?A RbOH solution is titrated four (4) times against potassium hydrogen phthalate (KHP; FW=204.224) samples to the Phenolphthalein endpoint. Using the data below, determine the concentration of the RbOH solution? g of KHP Volume of Base Required 0.5373 g 42.49 mL 0.5856 g 43.88 mL 0.5790 g 48.56 mL 0.5856 g 44.60 mL (Report your answer as "mean +/- std dev") M What is the percent relative standard deviation? % What is the 99% Confidence Interval for the concentration of the solution (population mean)?