Reagents to accomplish the following transformation are:(a) 1. (Sia) BH; H202 HO; 2. NazCr0, H3O"3. NH, heat; 4. POCI,(c) (Sia) BH; H,O, HO; 2. HCN, KCN(b) (Sia) BH; H,O, HO; 2. NABH CH,OH3. PBry 4. NACN, DMSO(d) 1. (Sia),BH; H2Og HO: 2. Na,Cr2O7, H3O*3. NH, heat; 4. LIAIH HOO aOc

The reaction mechanism adopted in the given reaction has been described below.

Reagents to accomplish the following transformation are: (a) 1. (Sia);BH; H;0a HO; 2. Na Cr0, HO" 3. NH, heat; 4. POCI, (c) (Sia) BH; H,O, HO: 2. HCN, KCN (b) (Sia);BH; H;O, HO: 2. NABH, CH,OH 3. PBry 4. NACN, DMSO (d) 1. (Sia),BH; H,O, HO: 2. Na,Cr2O, H;O* 3. NH, heat; 4. LIAIH, H,O

Reagents to accomplish the following transformation are: (a) 1. (Sia);BH; H;0a HO; 2. Na Cr0, HO" 3. NH, heat; 4. POCI, (c) (Sia) BH; H,O, HO: 2. HCN, KCN (b) (Sia);BH; H;O, HO: 2. NABH, CH,OH 3. PBry 4. NACN, DMSO (d) 1. (Sia),BH; H,O, HO: 2. Na,Cr2O, H;O* 3. NH, heat; 4. LIAIH, H,O

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution

Section16.SE: Something Extra

Problem 75AP: Phenols (ArOH) are relatively acidic, and the presence of a substituent group on the aromatic ring...

See similar textbooks

Related questions

Q: How would you Synthesize from beneyl the fellowing Molecule bromide. Cltz

A: In this question, we will synthesized the final product from the starting material benzyl bromide.…

Q: I I Least reactive Most reactive

A: SN1 reaction is substitution nucleophilic unimolecular reaction. Stability of reaction depend upon…

Q: The molecular formula of unknown compound B is C10H16.Quantitative brominationof a 0.473-g sample of…

Q: (b) Discuss the effect of ring strain on the internal c=0 stretching in cyclic alkenes ke tones

A: Answer -

Q: 6. Gee h resonansstruktuur vir die volgende verbinding en verduidelik hoekom dit stabieler compound…

A: Resonance is flow of pi or non bonding electrons from one part of conjugated system to other it…

Q: Under certain reaction conditions, 2,3-dibromobutane reacts with twoequivalents of base to give…

Q: (c) Write the products and comment on the natures of the following reactions :

A: organometallics reaction

Q: 7. The following SN2 reaction yields a product with the given empirical formula. Suggest a structure…

Q: Identify the structure of the oxygen-containing compound with m/z= 74 (M+ ), 56 and 31 from the ones…

A: The correct structure is B i.e. 1-butanol. The molecular ion peak M+ is at m/z = 74 indicates that…

Q: Alec wanted to prepare to diene B to use in a subsequent Diels-Alder reaction. He thought he could…

A: (a) Requirement from question: FT-IR data We will take FT- IR of the compound and will compare the…

Q: an eq i) a hydride, which hydroiyses rapidly and extensively in cold water. in A bydride which is

A: Hydride: Hydride are the compound that is formed by reaction of elements with hydrogen. For example…

Q: Which SN1 raction is faster in the given pair?

A: In the reaction it is said that reaction proceed by SN1 mechanism means there must be formation of…

Q: Which compound I or II is more basic? Justify your answer using orbital "cartoon" diagrams. CH3 CH3…

A: Compound one is more basic than two because lone pair of electrons on nitrogen atom is easily…

Q: Dwhich of the following conttains an electnon.rich A) H S s electron rich 8)CH30 )CH2CECH…

A: To identify: The electron-rich atoms in the given species.

Q: MCQ 124: Hydrogen bromide have comparatively more resistant to decomposition than A. hydrogen iodide…

Q: Please arrange the following according to increasing reactivity towards SN2.

A: SN2 stand for bimolecular nucleophilic substitution reaction

Q: 1. The following molecule has a molecular formula of C,H10O. The IR and 'H-NMR spectra of the…

A: Given

Q: Suggest an explanation for the observed order of SN1 reactivity of the following compounds.

A: SN1 reactions are obtained by forming the stable carbocation. These reactions proceeds through the 2…

Q: carbon and 345% hydrogen on the molar fonmula of the compound? (Relative atomic mass C-12.0, O-16.0,…

A: Given:- Molar mass of compound = 116 Relative composition of Carbon = 41.38% Relative composition…

Q: a How wod you prepar fulowing conpounds you may use any other magarta 777 LIAH, но HO Me MeMger

A: Reduction is the process of adding up of hydrogen atoms onto a functional group using certain…

Q: 4.Give two 4spets ook at the' structure of ad that need to be fultilled when made dye by diazo you…

A: These are generally made from primary aromatic amine in addition to nitrous acid.

Q: Compound A reacts with hydrogen to form cyclooctane. Upon reaction with 03, compound A forms 2 moles…

A: Given that a compound (A) reacts with hydrogen to obtain cyclooctane. Again the compound (A) on…

Q: hat is the purpose of adding CaCO3 or NaHCO3 in the Mohr Method determination of chloride? Than

A: the answer is as follows:

Q: and carbon dioxide after ozonolysis HO. after reacting with BH, and H,O, KOH

A: Given, And Give reactants of the given products .

Q: erentiate between El and E2 reactions by giving one example of each. EI E2 d) Draw the molecular…

Q: 9a. For each compound 1 and 2 draw a reasonable structure of the molecular ion он н но. HO Compound…

Q: -CH A в D O 1. Structures Cand D. O 2 Structures A andC 0 3. Structures B and D. O 4. Structures A…

A: Aromaticity is the property of the organic compounds which are cyclic, planar, and having resonance.…

Q: CO,Me

Q: (a) Explain how pyrrole is isoelectronic with the cyclopentadienyl anion.(b) Specifically, what is…

A: (a) The structures of the compounds pyrrole and cyclopentadienyl anion are represented below. The…

Q: 생생활나타내어라. 서로 다른 작용기 사이를 '네비게이트 할 수 있도록 어떻게 반응이 조합되는지를 알아보기 위해 로드맵을 참고하여라. 1. Brg le light 2.1 HBr in…

Q: Shaw haw T compaunds YOIC a.Smm cauld prepare the fallauing materials with the starting shawn and…

A: Hi, since there are multiple questions posted, we will answer first question. If you want any…

Q: CH CI CI 30 -75

A: A ring compound having conjugated system and planner and content (4n+2) number of Pi electron is…

Q: 39), Thionyl chaloride, sOcz orying ageet in meay syotetic chamistry experimepts isi used as a very…

Q: NH₂ OMe (i) PhCHO, cat. H+ (ii) BF3.OEt₂ SiMe3 Ph HN OMe

A: Steps of the organic transformation are given below:

Q: What is the structure of the compound with the following data?

A: As per guidilines if multiple questions are present, first question is allowed to answer, please…

Q: What dene and dienophile is needed to prepare the follow Choices a and b c and d e and f c and f b…

A: The reaction of both a and b reagents in option 'A' as well as c and d reagents in option 'B' will…

Q: The reaction between Pl3, PSCl3 and Zn powder gives P3ls as one of the products. The sołution state…

A: This Question is based upon P31 NMR.

Q: Provide detailed reaction mechanism and reagents required for the synthesis of B from А. Br A

A: Grignard reagent is prepared by inserting mg metal in the between carbon and halogen.

Q: Why As2O3 is first dissolved in base and then the resulting solution needs to be acidified before…

Q: A) B) :o: C) HO Name the following structures:

A: IUPAC Rule- Find and name the longest continuous carbon chain. Identify and name groups attached to…

Q: d) Reaction of the compound below with lithium aluminum hydride

A: The molecular formula for lithium aluminium hydride is LiAlH4 and it acts as a reducing agent for…

Q: Give a resonance structure for the following compound and explain why it is more stable than an…

Q: and carbon dioxide after ozonolysis HO after reacting with BH, and H,O, KOH

A: Given products are : And Identify the reactants = ?

Q: Hydrogenation of one mole of the triene A with one mole of H, gives isomeric dienes having molecular…

A: Woodward-Fieser Rules is used for Calculating the λmax of Conjugated Dienes and Polyenes.

Q: Compound A has the formula CH and is known not to contain any tripl 10"16 bonds. When treated with…

A: Compound A molecular formula is given as C10H16 , hence it's DOU is 3 Compound A upon…

Question

100%

Reagents to accomplish the following transformation are:
(a) 1. (Sia) BH; H202 HO; 2. NazCr0, H3O"
3. NH, heat; 4. POCI,
(c) (Sia) BH; H,O, HO; 2. HCN, KCN
(b) (Sia) BH; H,O, HO; 2. NABH CH,OH
3. PBry 4. NACN, DMSO
(d) 1. (Sia),BH; H2Og HO: 2. Na,Cr2O7, H3O*
3. NH, heat; 4. LIAIH HO
O a
Oc

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

give the reagents for parts a-p
Qn no. 20. Kindly provide proper explanation with all details for each step.
Explain how the reaction of (CH3)2CHCH(Cl)CH3 with H2O yields two substitutionproducts, (CH3)2CHCH(OH)CH3 and (CH3)2C(OH)CH2CH3
The above reaction involves heterolytic bond breakage of HBr a) Encircle the nucleophile (s) and electrophile (s) and explain why. b) Give the mechanism of the reaction by: ) Drawing the appropriate arrows to track the flow of electrons in Showing the species formed after bond breakage and bond formation with appropriate charges. c) Predict the final products.
Nicotinic acid, more commonly named niacin, is one of the B vitamins. Show how nicotinic acid can be converted to (a) ethyl nicotinate and then to (b) nicotinamide.
3 b and c） Give the product
Acetoxybenzene (PhOC(=O)OCH3) is much less reactive than ethoxybenzene (PhOCH2CH3) in electrophilic aromatic substitution reactions. Suggest an explanation for this result, based on an analysis of the inductive and resonance electronic effects of the two substituents on the stability of theWheland intermediate for para substitution by an electrophile E+
Enamines formed from the cyclic secondary amine pyrrolidine are important intermediates in the synthesis of 1,5-diketones. (1st pic) On the structures provided below, draw arrows showing electron flow for the reaction mechanism for the acetic acid-catalyzed formation of an enamine from cyclohexanone and pyrrolidine. (2nd pic)
Chemistry Give the products of the reaction of 1 mole of 2-methy1-1,3-pentadiene with 1 mole of HBr. Whichproduct(s) will predominate if the reaction is under kinetic control? Which products) will predominateif the reaction is under thermodynamic control?
How do you decompose KHS2O3
Give a proposal on the synthesis methods of CoSO4.7H2O
Compound A (C9H12) absorbed 3 equivalents of H2 on catalytic reduction over apalladium catalyst to give B (C9H18). On ozonolysis, compound A produced 3 products, C, Dand E which was a ketone identified as cyclohexanone. On treatment with NaNH2 in NH3,followed by addition of iodomethane, compound A gave new hydrocarbon, F (C10H14). Drawstructures of A, B, C, D and F.