Save Answer Question 2 The ionization constant (Ka) equation of a monoportic weak, HA, acid is given by ca- K, = (1-a) The use of conductivity meter to test a 0.106 M solution of this weak acid gives a specific conductance, K, 20.24 µS.cm-1. What would be the pka, (-long Ka), of the acid, if its limiting molar ionic conductivities are y = 243 and A. = 74 S.cm2 mol"1 ? O A. 5.53 ОВ. 3.12 OC.6.00 OD.4.41 ОЕ 3.62
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- A solution of Ba(OH)2 was standardized against0.1215 g of primary-standard-grade benzoic acid, C6H5COOH (122.12 g/mol). An end point was observedafter addition of 43.25 mL of base. (a) Calculate the molar concentration of the base. (b) Calculate the standard deviation of the molarconcentration if the standard deviation for themass measurement was ±0.3 mg and that for thevolume measurement was ±0.02 mL. (c) Assuming an error of ±0.3 mg in the mass measurement,calculate the absolute and relative systematicerror in the molar concentration.0.5M HA sample with 0.2 dissociation; It is placed in a conductivity cell with a length of 0.9 cm and an area of 2 cm2 and its conductivity is read as 300 mS. For this purpose;a) Equivalent conductivity of the electrolyte ?b) Boundary equivalent conductivity ?c) Decomposition constant ?1. What is the MW of the analyte?2. What is the meq of the analyte?3. What will be the weight (in grams) of the analyte if the standardization is to be quartered?4. What will be Normality of the solution if 7.5ml of the titrant was consumed in the standardization?5. What is the average Normality if two or more trials were conducted with the values of 0.102N and 0.105N?
- A water contains 50.40 mg · L−1 as CaCO3 of carbon dioxide, 190.00 mg · L−1 as CaCO3 of Ca2+ and 55.00 mg · L−1 as CaCO3 of Mg2+. All of the hardness is carbonate hardness. Using the stoichiometry of the lime soda ash softening equations, what is the daily sludge production (in dry weight, kg · day−1) if the plant treats water at a rate of 2.935 m3 · s−1? Assume that the effluent water contains no carbon dioxide, 30.0 mg · L−1 as CaCO3 of Ca2+ and 10.0 mg · L−1 as CaCO3 of Mg2+. Be sure to calculate the mass of CaCO3 and Mg(OH)2 sludge produced each day.A sample containing iron is approximately 99.0% w/w Fe. Using ammonia, iron is precipitated as Fe (OH)3 which is ignited to Fe203. (a) What is the gravimetric factor for analyte Fe (AW=55.85 g/mol) and precipitate Fe203 (FW=159.69 g/mol)? (b) What mass of sample is needed to ensure that the Fe203 precipitate would weigh at least 1.00 g?The data below was obtained with a Cl- ISE to prepare a plot of mV vs. log[Cl-]. Assume the unknown saltwater solution was diluted as in the procedure before being measured. What is the ppm Cl- of the undiluted unknown solution? Cl- Concentration (ppm) Potential (mV) 10 160 100 94 1000 40 Diluted Unknown Saltwater 132
- A 0.1475-M solution of Ba(OH)2 was used to titrate the acetic acid (60.05 g/mol) in a dilute aqueous solution. The following results were obtained. (See attached image)(a) Calculate the mean w/v percentage of acetic acid in the sample.(b) Calculate the standard deviation for the results.(c) Calculate the 90% confidence interval for the mean.(d) (d) At the 90% confidence level, could any of the results be discarded?At 25°C the equivalent conductivities of dilute NaI solutions are as following:Find Λ° of NaI at 25°CAssume that a solute has a D* of 2.03 x 10-9 m2 / Sec and that w is equal to 0.5. If landfill leachate with a chloride concentration is next to a clay liner that is 2 m thick and the concentration of chloride is 2315 mg/L, what would be the chloride concentration at the outside of the liner after 25 years of diffusion. ? ignore any effects of advection. Defining a "release" from the landfill as a concentration exceeding 1 mg/l, how long will it take for a release to occur by diffusion alone? Provide answer in years to the nearest tenth. Eg: 10.3
- Consider the titration illustrated in Figure 8.] Anhydrous sodium carbonate (Na₂CO₃) is a primary standard. When 0.364 grams of the substance is placed in a conical flask, then 20.00 cm³ of sulphuric acid (H₂SO₄) solution is required to reach the end point of the titration. What is the concentration in mol·dm⁻³ of the sulphuric acid solution? [Give the answer to 3 decimal places. Do not type in the unit. Use a decimal point.] *In the volumetric analysis of a 0.5000g sample of a silver coin containing 90.00% Ag, what is the least normality that a KSCN solution may have and not require more than 10.00mL of it in the titration of the Ag?A first-stage recovery of magnesium from seawater is precipitationof Mg1OH22 with CaO:Mg2+(aq) + CaO(s) + H2O(l)---->Mg(OH)2(s) + Ca2+(aq) What mass of CaO, in grams, is needed to precipitate 1000lb of Mg(OH)2?