Silver Nitrate (AgNO3) at a concentration of 0.0500M is being utilized to titrate a mixture of 0.01000 M K2CO3 and 0.01000 M NaIO3.   A) Which anion will precipitate first? Ksp = 3.1 x 10-8 for AgIO3 Ksp = 8.1 x 10-12 for Ag2CO3. Show how you arrived at your answer.   B) Can 95% of the first anion that is precipitated be titrated without causing the precipitation of the second? Show how you arrived at your answer by calculation starting with 50.00 mL of the solution. Be sure to account for dilution in your calculation

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.35QAP
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Silver Nitrate (AgNO3) at a concentration of 0.0500M is being utilized to titrate a mixture of 0.01000 M K2CO3 and 0.01000 M NaIO3.

 

A) Which anion will precipitate first? Ksp = 3.1 x 10-8 for AgIO3 Ksp = 8.1 x 10-12 for Ag2CO3. Show how you arrived at your answer.

 

B) Can 95% of the first anion that is precipitated be titrated without causing the precipitation of the second? Show how you arrived at your answer by calculation starting with 50.00 mL of the solution. Be sure to account for dilution in your calculation

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