The cations in an aqueous solution that contains 0.150 M Ba(NO3)2 and 0.0800 M Ca(NO3)2 are to be separated by taking advantage of the difference in the solubilities of their sulfates. Ksp(BaSO4) = 1.1 × 10-10 and Ksp(CaSO4) = 2.4 × 10-5 . What should be the concentration of sulfate ion for the best separation?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
Problem 67CP
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The cations in an aqueous solution that contains 0.150 M Ba(NO3)2 and 0.0800 M Ca(NO3)2 are to be separated by taking advantage of the difference in the solubilities of their sulfates. Ksp(BaSO4) = 1.1 × 10-10 and Ksp(CaSO4) = 2.4 × 10-5 . What should be the concentration of sulfate ion for the best separation?

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