Sn2 and N (starting concentration 10 mol/L) should be separated byfractionated precipitation using H₂S. Does a pH range exist allowing tocompletely precipitate one metal (i.e. the remaining concentration of theprecipitated ion has to be 10 mol/L or less) whereas the other stays insolution at its initial concentration? Please calculate this pH range whereby pHvalues below zero are set to zero! Please illustrate the situation graphically byplotting pH versus in solution/precipitating/fully precipitated for the two ions (9)Solubility product (SnS): 10; (NIS): 1021;Acid constant (H2S): 10-20,r/Concentration of H2S in water: 0.1 mol/L

These points illustrate the pH range where one metal ion can be completely precipitated while the…

Answered: Sn2 and N (starting concentration 10…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter15: Acid–base Equilibria

Section: Chapter Questions

Problem 107AP

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The following text may be found at the ThermoFisher website: "PBS (phosphate buffered saline) is a pH-adjusted blend of ultrapure-grade phosphate buffers and saline solutions which, when diluted to a 1X working concentration, contains 137 mM NaCl, 2.7 mM KCl, 8 mM Na2HPO4, and 2 mM KH2PO4. Each 10X PBS solution is ready to use upon dilution to the desired concentration." This means that the product that you purchase has a concentration 10 times the concentration at which it is used. 1. Look up the pKa values for phosphoric acid and list them as a part of your response. 2. Based on the description of the contents of the PBS buffer, calculate the pH of the 1X solution. 3. Assume that you wish to use a pH = 7.00 buffer. If your answer to 2 was more acidic than pH 7.00, calculate how much 1.00 M NaOH you would need to add to get to pH = 7.00. If your answer to 2 was more basic than pH 7.00, calculate how much 1.00 M HCl you would need to add to get to pH = 7.00.
a) At temperature 25°C, 0.02 M hydrazine, N2H4 solution is 0.69% ionised. Calculate the i. Concentration of OH- ion ii. ionisation constant, Kb b) Calculate the mass of sodium benzoate, C6H5COONa that should be added to 500 mL of 0.2M aqueous benzoic acid, C6H5COOH solution to produce a buffer with pH 3.50?[ Ka for C6H5COOH = 6.3 x10-5] c) When a 1 x 10-3 moldm-3 solution of CaCl2 is mixed with an equal volume of a 1 x 10-3 moldm-3 solution of Na2SO4, will precipitate form? (Ksp CaSO4= 2 x 10-5) Do you mean that pH? That was all the given information the question gave.. I don't understand how to use the ionised part the most
b) In the development of a method for the determination of formic acid by neutralization volumetry, the pH was calculated as a function of the addition of NaOH for the titration of 25.00 mL of 0.1280 mol/L formic acid with NaOH standardized with concentration of 0.0670 mol/L. With reference to this titration curve, determine the pH of the solution after the addition of 5.00 mL of titrant and at the equivalence point. Data: Ka=1.70x10-4. Present the results with two places after the comma and show your calculations. c) Based on the table below, indicate which indicators could be used to determine the end point of this titration.
What reagent might be used to separate the ions in each of the following mixtures, which are 0.1 M with respect to each ion? In some cases it may be necessary to control the pH. (Hint: Consider the Ksp values given in Appendix J.) (a) Hg22+ and Cu2+ (b) SO42− and Cl– (c) Hg2+ and Co2+ (d) Zn2+ and Sr2+ (e) Ba2+ and Mg2+ (f) CO32− and OH–
Consider exactly one litre of a propanoic acid buffer solution, containing 0.600 M C3H5OOH and 0.252 M C3H5OO- . 1.1 Determine the pH of the buffer solution. - You may use “HA” to denote the formula of the acid. - You may make certain assumptions to simplify your calculations - Ka for hydrofluoric acid is 1.3 × 10−5 . 3.2 Determine by means of a full calculation the change in pH of the buffer solution that will result when 100. mL of a 1.00 × 10−2 M HCℓ solution is added to it. You must indicate all the relevant reaction equations in your working.
Can someone please explain why and how the step 1 was done? What was its purpose? Why was only the pKa2 value was used in the second step 2? I don't understand shortcuts and I would appreciate it if it's explained step by step. This was the solution to my previous question in which I asked: What is the pH of a buffer prepared by mixing 100 mL 0.050 mM NaH2PO4 and 25 mL 0.075 mM Na2HPO4? (pKa1=2.2; pKa2= 7.21; pKa3=12.7)
Zn²+ and Mn²+ (starting concentration 102 mol/L) should be separated by fractionated precipitation using H₂S. Does a pH or pH range exist allowing to completely precipitate one metal (i.e. the remaining concentration of the precipitated ion has to be 105 mol/L or less) whereas the other stays in solution at its initial concentration? Please calculate this pH range!
In developing a method for the determination of formic acid by neutralization volumetry, an analyst calculated the pH as a function of the addition of NaOH for the titration of 30.00 mL of 0.1280 mol/L formic acid with standardized NaOH with concentration of 0.1570 mol/L. With respect to this titration curve, determine the pH of the solution after adding the following volumes of NaOH: 0.00 mL; 10.00 ml; 25 mL of titrant and at the equivalence point. Data: Ka=1.70x10-4. Present the results with two decimal places and show your calculations.
What happens when too much NaSCN is prepared in solution of mixtures of standard solutions of Fe(NO3)3 and NaSCN, so that [SCN^-] is higher than expected? What does this do to the measured Keq?
Many chemical reactions are carried out in the presence of buffers. Use the Henderson-Hasselbalch equation to provide a recommendation for a suitable acete/acetic acid buffer under the following reaction conditions. a) If a checial reaction produces hydroxide ion, OH-, what would be the range for the target pH of a buffer soution that would favor pH stabilizatoin under these conditions? Explain.
For the adjustment of 0.1 M HCl standard solution, 0.1345 g Na2CO3 in primary standard purity was weighed, dissolved in 50 mL of distilled water and titrated with HCl solution. As a result of the titration, 14 mL of acid solution was consumed. Accordingly, what is the true concentration of the HCl solution?
The first step in purifying the urine collected on the ISS is to treat every liter of urine with 20 mL of 1.0 M H2SO4. To simplify the calculations, lets assume that urine is water. a) What is the pH of a solution of 20. mL of 1.0 M H2SO4 added to 1.00 L water? To determine this, you can safely assume that 100% of the H2SO4 reacts to form H3O+ and HSO4- ions. Use pKa2 (1.92) to determine if any more protons are added to the solution from HSO4-.

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