Spectrophotometric Determination of a Metal A 100.00 mL of exactly 250.0 mg/L Cu2+ stock solution was prepared using a 99.95% pure Ču(NO3)2·3H2O (241.60 g/mol). From this stock, a series of standard solutions were prepared by pipetting certain volumes into 100-mL volumetric flasks, followed by adding 2.00 mL of concentrated NH3, and finally diluting to mark with deionized water. Additionally, a blank solution was prepared by using only NH3 and distilled water. Question: Why was NH3 added to each standard solution before diluting with distilled water? What will be the resulting color of the solution and why is this the color that is observed?

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter15: Molecular Luminescence Spectrometry
Section: Chapter Questions
Problem 15.10QAP
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Spectrophotometric Determination of a Metal
A 100.00 mL of exactly 250.0 mg/L Cu2+ stock solution was prepared
using a 99.95% pure Cu(NO3)2-3H20 (241.60 g/mol). From this stock, a
series of standard solutions were prepared by pipetting certain volumes
into 100-mL volumetric flasks, followed by adding 2.00 mL of concentrated
NH3, and finally diluting to mark with deionized water. Additionally, a blank
solution was prepared by using only NH3 and distilled water.
Question:
Why was NH3 added to each standard solution before diluting with distilled
water? What will be the resulting color of the solution and why is this the
color that is observed?
Transcribed Image Text:Spectrophotometric Determination of a Metal A 100.00 mL of exactly 250.0 mg/L Cu2+ stock solution was prepared using a 99.95% pure Cu(NO3)2-3H20 (241.60 g/mol). From this stock, a series of standard solutions were prepared by pipetting certain volumes into 100-mL volumetric flasks, followed by adding 2.00 mL of concentrated NH3, and finally diluting to mark with deionized water. Additionally, a blank solution was prepared by using only NH3 and distilled water. Question: Why was NH3 added to each standard solution before diluting with distilled water? What will be the resulting color of the solution and why is this the color that is observed?
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