In the acetic ačid determination in vinegar experiment; NaOH was standardized with 0.35 g KHP (molar mass = 204.22 g/mol). The KHP was dissolved in 75.0 mL distilled water in a 250 mL Erlenmeyer flask and titrated to the endpoint colour by dispensing 17.10 mL of NaOH from the burette. Calculate the molarity of NaOH. O a. 0.35 M O b. 0.25 M Oc. 0.15 M
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- Q: The concentration of the sulphate ion in a mineral water can be determinedby the turbidity which results from the addition of excess BaCl2, to a quantityof measured sample. A turbidometer used for this analysis has been standardisedwith a series of standard solutions of NaSO4. The following resultswere obtained:Standard solution Conc. (SO4)2− (mg/L) Reading of turbidometerS0 0.00 0.06S1 5.00 1.48S2 10.00 2.28S3 15.00 3.98S4 20.00 4.61i. In supposing that a linear relationship exists between the readings takenfrom the apparatus and the sulphur ion concentration, derive an equationrelating readings of the turbidometer and sulphate concentration(method of least squares).ii. Calculate the concentration of sulphate in a sample of mineral waterfor which the turbidometer gives a reading of 3.67.In an experiment to determine the concentration of H2SO4 in a brand of toilet cleanser, 10.0 cm3 of the cleanser was first diluted to 250.0 cm3 with distilled water. 25.0 cm3 of the diluted cleanser were titrated with 0.320 mol dm–3 NaOH solution, using methyl orange as indicator.If 29.2 cm3 of NaOH solution is used, what is the concentration of H2SO4 in the undiluted toilet cleanser?a. 2.30 mol dm–3b. 4.60 mol dm–3 c. 9.20 mol dm–3 d. 11.50 mol dm–350 cm3 of 0.05 M weak acid solution is titrated with 0.1 M NaOH solution. The measured pH valuesare 7.345 and 7.497 at the consumptions of 6.0 and 6.1 cm3, respectively. What value of the buffer capacity can be calculated in the solution at pH = 7.421?
- A 0.1 M solution of acid was used to titrate 10 ml of 0.1 M solution of alkali and thefollowing volumes of acid were recorded: 9.88 10.18 10.23 10.39 10.21 Calculate the 95% confidence limits of the mean and use them to decide whetherthere is any evidence of systematic error.You have a solution that contains acetic acid, (CH3COOH or HAc). The concentration of acetic acid in the aqueous solution is 0.35 mol / dm3. Ka = 1.7378 x 10 ^ -5 M a. Calculate the pH of the solution. 15 cm 3 of the acetic acid solution was titrated with sodium hydroxide solution, NaOH (aq), at a concentration of 0.5 mol / dm3 b. Describe how you would proceed to perform a titration of an acid of unknown concentration. What information can be obtained from a titration, describe the different phases. c. How much NaOH will be added when the equivalence point occurs?The concentration of ammonia in a cleaning product was determined by back titration.Firstly, 10.00 cm3 of the cleaning product was pipetted into a large conical flask,containing 250.00cm3 of 0.50 mol/l HCl to give Solution A.Following a period of reaction and shaking, 50.00cm3 of Solution A was removed anddiluted to 250 cm3 with water in a volumetric flask to give Solution B.20 cm3 samples of Solution B were titrated against 0.05 mol/l Na2CO3 solution, givingan average titre of 12.45 cm3. i) Write equations for the reactions that have taken place.ii) Determine the concentration of NH3 in the original cleaning product in mol/l,g/l, ppm, and % w/v.
- One gram of sodium hydroxide (NaOH) is used to adjust the pH of an aqueous solution (200 gallons) thatcontains 10 lbs of finely ground rhodochrosite (MnCO3) ore. Does the NaOH raise or lower the solutionpH? What is the amount of NaOH added in lbs/ton? What is the molarity (mol/l) of the system? Assumingthe NaOH is completely soluble and the system is at room temperature, what is the solid-to-liquid ratio(wt%) of the system?A 110.00 mL solution of 0.00195 M A3B2 is added to a 160.00 mL solution of 0.00155 M C3D4. What is pQsp for A3D2?For titration for determination of Chloride, 0.05 AgNO3 and NaCl with a 5% (w/v) K2CrO4 indicator, what is the % (w/w) Cl- using the atomic weight for Chlorine. Data below: Primary standard weight 0.1173g , 0.1056g , and 0.1049g Vol of titrant delivered 35.47mL , 31.75mL, and 31.04mL Uknown Chloride mass 0.1527g, 0.1442g, and 0.1337g Vol of titrant delivered 40.00mL ,37.68mL ,and 34.96 mL
- A dried sample of commercial salt was prepared by a coning and quartering. A 0.911-g sample of the salt was dissolved and diluted to 250.0 mL in a volumetric flask. Repeat 10.00-mL aliquots of this solution were titrated with a 0.054 M silver nitrate solution, requiring 9.68 mL to reach equivalence. Calculate the %(w/w) NaCl in the original sample.The solution of total volume 0.50 L was prepared by the addition of 0.10 moles of KF to sifficient water. What are the major species of the solution and pH ?b. A student has a sea water sample which contains Ca2+ ions . Describe briefly how he willdetermine the concentration of Ca2+ ion in the sample using a simple titration. Explain the colourchanges at the endpoint. Which medium is suitable for performing the titration, acidic or basic medium and why?