Answered: Starting from the definition of Cp and…

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Starting from the definition of Cp and Cv, derive the expression of (Cp-Cv) expressed only in measurable quantities.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter6: Equilibria In Single-component Systems

Section: Chapter Questions

Problem 6.56E

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Question

T as
- ²), - (),
1
N
N әт
dT
P
P
P
as
²₂ = T (²),
ат
²y = 7 (²)
Cy T
T
as
1
- ² (²) ₁ - ² (19),
(35)
N
N dT
V
V
V

Starting from the definition of Cp and Cv, derive the expression of (C₁-Cv) expressed only
in measurable quantities.

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