Step 1: CH4(g) + Cl2(g) <--> CH3(g) + HCl(g) + Cl slow Step 2: CH3(g) + Cl2(g) --> CH3Cl(g) + Cl fast A. What is the overall reaction and rate expression for the appearance of CH3Cl (g) ? B. Use the answer in part a to write the rate expression for the change in concentration of CH3(g). C. Using the steady state approximation, give an expression for the appearance of CH3Cl(g) that does not depend on the concentration of CH
Step 1: CH4(g) + Cl2(g) <--> CH3(g) + HCl(g) + Cl slow Step 2: CH3(g) + Cl2(g) --> CH3Cl(g) + Cl fast A. What is the overall reaction and rate expression for the appearance of CH3Cl (g) ? B. Use the answer in part a to write the rate expression for the change in concentration of CH3(g). C. Using the steady state approximation, give an expression for the appearance of CH3Cl(g) that does not depend on the concentration of CH
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 94QAP: Three first-order reactions have the following activation energies: (a) Which reaction is the...
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Step 1: CH4(g) + Cl2(g) <--> CH3(g) + HCl(g) + Cl slow
Step 2: CH3(g) + Cl2(g) --> CH3Cl(g) + Cl fast
A. What is the overall reaction and rate expression for the appearance of CH3Cl (g) ?
B. Use the answer in part a to write the rate expression for the change in concentration of CH3(g).
C. Using the steady state approximation, give an expression for the appearance of CH3Cl(g) that does not depend on the concentration of CH3(g). (Step 1 is reversible, step 2 is not)
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