! ( answer with explanation ) Some PClg is allowed to dissociate into PCl, and Cl, at 523 K. At equilibrium, [PCL3] = 0.129 M, and [PCl] =[Ch] = 8.03×102 M Additional PCI3 is added so that [PC13]new= 0.127 M and thesystem is allowed to once again reach equilibriumPCI3(g) PCI3(g) + Cl2(g)K= 5.01×10² at 523 K(a) In which direction will the reaction proceed to reach equilibrium? to the left v(b) What are the new concentrations of reactants and products after the system reaches equilibrium?[PCI5] =[PCI3] =MM[C2] =

Answered: Image /qna-images/answer/19d31664-bee4-4879-a9c5-570d767e3dcb.jpg

system is allowed to once again reach equilibrium. PCI5(g) PCI3(g) + Cl2(g) K= 5.01×10² at 523 K (a) In which direction will the reaction proceed to reach equilibrium? to the left v (b) What are the new concentrations of reactants and products after the system reaches equilibrium? [PC|3] =| (PCI) = [ (C] =| M M M

system is allowed to once again reach equilibrium. PCI5(g) PCI3(g) + Cl2(g) K= 5.01×10² at 523 K (a) In which direction will the reaction proceed to reach equilibrium? to the left v (b) What are the new concentrations of reactants and products after the system reaches equilibrium? [PC|3] =| (PCI) = [ (C] =| M M M

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter12: Chemical Equilibrium

Section: Chapter Questions

Problem 62QRT

See similar textbooks

Similar questions

Kc = 5.6 1012 at 500 K for the dissociation of iodine molecules to iodine atoms. I2(g) 2 I(g) A mixture has [I2] = 0.020 mol/Land [I] = 2.0 108 mol/L. Is the reaction at equilibrium (at 500 K)? If not, which way must the reaction proceed to reach equilibrium?
A solution is prepared by dissolving 0.050 mol of diiodocyclohexane, C5H10I2, in the solvent CCl4.The total solution volume is 1.00 L When the reaction C6H10I2 C6H10 + I2 has come to equilibrium at 35 C, the concentration of I2 is 0.035 mol/L. (a) What are the concentrations of C6H10I2 and C6H10 at equilibrium? (b) Calculate Kc, the equilibrium constant.
Methanol can be synthesized by means of the equilibriumreaction CO(g)+2H2(g)CH3OH(g) for which the equilibrium constant at 225°C is 6.08103. Assume that the ratio of the pressures of CO(g) and H2(g) is 1:2. What values should they have if the partial pressureof methanol is to be 0.500 atm?
Phosgene, COCl2, used in the manufacture of polyurethane plastics, is prepared from CO and Cl2. CO(g)+Cl2(g)COCl2(g) An equilibrium mixture at 395C contains 0.012 mol CO and 0.025 mol Cl2 per liter, as well as COCl2 If Kc at 395C is 1.23 103, what is the concentration of COCl2?
For the equilibrium 2 SO2(g) + O2(g) 2 SO3(g) Kc = 245 (at 1000 K) the equilibrium concentrations are [SO2] = 0.102, [O2] = 0.0132, and [SO3] = 0.184. The concentration of SO2 is suddenly doubled. Show that the forward reaction takes place to reach a new equilibrium.
Solid ammonium iodide decomposes to ammonia and hydrogen gases at sufficiently high temperatures. NH4I(s)NH3(g)+HI(g)The equilibrium constant for the decomposition at 400C is 0.215. Twenty grams of ammonium iodide are sealed in a 7.50-L flask and heated to 400C. (a) What is the total pressure in the flask at equilibrium? (b) How much solid NH4I is left after the decomposition?
Many sugars undergo a process called mutarotation, in which the sugar molecules interconvert between two isomeric forms, finally reaching an equilibrium between them. This is true for the simple sugar glucose, C6H12O6, which exists in solution in isomeric forms called alpha-glucose and beta-glucose. If a solution of glucose at a certain temperature is analyzed, and it is found that the concentration of alpha-glucose is twice the concentration of beta-glucose, what is the value of K for the interconversion reaction?
At 2300 K the equilibrium constant for the formation of NO(g) is 1.7 103. N2(g) + O2(g) 2 NO(g) (a) Analysis shows that the concentrations of N2 and O2 are both 0.25 M, and that of NO is 0.0042 M under certain conditions. Is the system at equilibrium? (b) If the system is not at equilibrium, in which direction does the reaction proceed? (c) When the system is at equilibrium, what are the equilibrium concentrations?
Sulfur oxychloride, SO2Cl2, decomposes to sulfur dioxide and chlorine gases. SO2Cl2(g)SO2(g)+Cl2(g) At a certain temperature, the equilibrium partial pressures of SO2, Cl2, and SO2Cl2 are 1.88 atm, 0.84 atm, and 0.27 atm, respectively. (a) What is K at that temperature? (b) Enough Cl2 condenses to reduce its partial pressure to 0.68 atm. What are the partial pressures of all gases when equilibrium is reestablished?
The equilibrium constant for the butane iso-butane equilibrium at 25 C is 2.50. Calculate rG at this temperature in units of kJ/mol.
Consider the same reaction as in Question 11. In one experiment 1.0 mole of H2O(g) and 1.0 mole of CO(g) are put into a flask and heated to 350C. In a second experiment 1.0 mole of H2(g) and 1.0 mole of CO2(g) are put into another flask with the same volume as the first. This mixture is also heated to 350C. After equilibrium is reached, will there be any difference in the composition of the mixtures in the two flasks?
The following data are for the system A(g)2B(g) (a) How long does it take the system to reach equilibrium? (b) How does the rate of the forward reaction compare with the rate of the reverse reaction after 30 s? After 90 s?