t of pt pt pt H- H- H- -OH -OH -OH CH₂OPO,² Ribose 5-phosphate NAIXE H-N-Enzyme H-C CHO -OH CH₂OPO, Glyceraldehyde 3-phosophate Conversion of ribose 5-phosphate to glyceraldehyde 3-phosphate (see above) is a step in the pentose phosphate degradation pathway. Write a detailed mechanism for the reaction above, then draw curved arrows to depict electron reorganization for step 5, the first step in hydrolysis of the iminium group below. Draw arrows to give enolates in the oxide resonance form. Arrow-pushing Instructions H-C-0-H H H :8-H + CHO CH₂OPO,

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter29: The Organic Chemistry Of Metabolic Pathways
Section29.SE: Something Extra
Problem 22MP
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t
of
pt
pt
pt
fpt
H-
H-
H-
-OH
-OH
-OH
CH₂OPO,²
Ribose
5-phosphate
Arrow-pushing Instructions
XW
H-N-Enzyme
H-C
CHO
"tom
H-
-OH
Conversion of ribose 5-phosphate to glyceraldehyde 3-phosphate (see above) is a step in the pentose phosphate degradation pathway. Write
a detailed mechanism for the reaction above, then draw curved arrows to depict electron reorganization for step 5, the first step in
hydrolysis of the iminium group below.
Draw arrows to give enolates in the oxide resonance form.
H-C-0-H
H
CH₂OPO,²
Glyceraldehyde
3-phosophate
+
:0-H
H
CHO
CH₂OPO,
Previous
Transcribed Image Text:t of pt pt pt fpt H- H- H- -OH -OH -OH CH₂OPO,² Ribose 5-phosphate Arrow-pushing Instructions XW H-N-Enzyme H-C CHO "tom H- -OH Conversion of ribose 5-phosphate to glyceraldehyde 3-phosphate (see above) is a step in the pentose phosphate degradation pathway. Write a detailed mechanism for the reaction above, then draw curved arrows to depict electron reorganization for step 5, the first step in hydrolysis of the iminium group below. Draw arrows to give enolates in the oxide resonance form. H-C-0-H H CH₂OPO,² Glyceraldehyde 3-phosophate + :0-H H CHO CH₂OPO, Previous
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