Tartaric acid is an inexpensive and readily available chiral starting material for the syn- thesis of chiral molecules. In a well-known prostaglandin synthesis, the (S,S)-tartaric acid enantiomer was used to prepare the chiral diol in several steps. The chiral diol was isolated as a synthetic intermediate, and the following reagents are used. Draw the structures of synthetic intermediates A and B. H3C- HO НО HO, Several steps ОН Nal НО ОН A В Pyridine Acetone (S,S)-Tartaric acid
Tartaric acid is an inexpensive and readily available chiral starting material for the syn- thesis of chiral molecules. In a well-known prostaglandin synthesis, the (S,S)-tartaric acid enantiomer was used to prepare the chiral diol in several steps. The chiral diol was isolated as a synthetic intermediate, and the following reagents are used. Draw the structures of synthetic intermediates A and B. H3C- HO НО HO, Several steps ОН Nal НО ОН A В Pyridine Acetone (S,S)-Tartaric acid
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter10: Alcohols
Section: Chapter Questions
Problem 10.59P
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