The amount of CaCO3 (s) in a rock sample shall be determined using gas volume geometry. The sample is added with excess hydrochloric acid and the gas which is then collected is collected over water. Explain how you can determine the amount of CaCO3 (s) in the sample by measuring the volume of gas generated. Suppose the experiment is performed at 25.0 ° C and a pressure of 1.00 atm. The measured volume of gas is 50.0 mL. How many grams of CaCO3 (s) is there in the sample? The water vapor pressure at 25 ° C is 23.76 mmHg. How much systematic error in the number of grams of CaCO3 (s) will we get if we do not take the water vapor pressure into account?
Ideal and Real Gases
Ideal gases obey conditions of the general gas laws under all states of pressure and temperature. Ideal gases are also named perfect gases. The attributes of ideal gases are as follows,
Gas Laws
Gas laws describe the ways in which volume, temperature, pressure, and other conditions correlate when matter is in a gaseous state. The very first observations about the physical properties of gases was made by Robert Boyle in 1662. Later discoveries were made by Charles, Gay-Lussac, Avogadro, and others. Eventually, these observations were combined to produce the ideal gas law.
Gaseous State
It is well known that matter exists in different forms in our surroundings. There are five known states of matter, such as solids, gases, liquids, plasma and Bose-Einstein condensate. The last two are known newly in the recent days. Thus, the detailed forms of matter studied are solids, gases and liquids. The best example of a substance that is present in different states is water. It is solid ice, gaseous vapor or steam and liquid water depending on the temperature and pressure conditions. This is due to the difference in the intermolecular forces and distances. The occurrence of three different phases is due to the difference in the two major forces, the force which tends to tightly hold molecules i.e., forces of attraction and the disruptive forces obtained from the thermal energy of molecules.
The amount of CaCO3 (s) in a rock sample shall be determined using gas volume geometry. The sample is added with excess hydrochloric acid and the gas which is then collected is collected over water. Explain how you can determine the amount of CaCO3 (s) in the sample by measuring the volume of gas generated.
Suppose the experiment is performed at 25.0 ° C and a pressure of 1.00 atm. The measured volume of gas is 50.0 mL. How many grams of CaCO3 (s) is there in the sample?
The water vapor pressure at 25 ° C is 23.76 mmHg. How much systematic error in the number of grams of CaCO3 (s) will we get if we do not take the water vapor pressure into account?
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