The determination of cyanide ions (CN-) is carried out according to the Mohr method: a titrating solution of silver nitrate (AgNO3) is gradually added to the aqueous sample until a red precipitate corresponding to the silver (I) chromate (Ag2CrO4) appears. To observe the titration end point, a small amount of Sodium Chromate is added to the aqueous sample. From the solubility product of Ag(CN)(s), calculate the maximum concentration of Ag+ ions allowed in solution in equilibrium with the solid phase.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter16: Solubility And Precipitation Equilibria
Section: Chapter Questions
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The determination of cyanide ions (CN-) is carried out according to the Mohr method: a titrating solution of silver nitrate (AgNO3) is gradually added to the aqueous sample until a red precipitate corresponding to the silver (I) chromate (Ag2CrO4) appears. To observe the titration end point, a small amount of Sodium Chromate is added to the aqueous sample. From the solubility product of Ag(CN)(s), calculate the maximum concentration of Ag+ ions allowed in solution in equilibrium with the solid phase.

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