The equilibrium composition of the mixture at 425°C will be independent of the pressure The vessel willcoutain hydrogen, iodine and Which of the following statements about the L diagram above are true? When A and B are mixed, there will be an inerease in vapour pressure This type of curve could "be obtained if A were carbon tetrachloride and B ethanol hydrogen iodide When dynamic equilibrium is attained the composition of the mixture remains constant Which of the following processes represent A mixture of 30cm' of A and 30cm of B 47. oxidation? Na +e Na Br +e Br 25,0 will have a volume greater than 60 cm' 46. If hydrogen io fide is heated in a élosed vessel to a temperai ire of 425°C and then maintained at 425 C 2. S,0 +2eV Instructions for questions 48-50

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Chapter30: Kinetic Methods Of Analysis
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Problem 30.14QAP
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Answer Q45, 46, 47

The equilibrium composition of the mixture
at 425°C will be independent of the pressure
The vessel will coutain hydrogen, iodine and
A Which of the following statements about the
diagram above are true?
When A andB are mixed, there will be an increase
in vapour pressure
This type of curve could be obtained if A were
carbon tetrachloride and B ethanol
3.
will have a volume greater than 60 em
1.
LAT
hydrogen iodide
When dynamic equilibrium is attained the
composition of the mixture remains constant
Which of the following processes represent
man
12g
A mixture of 30cm of A and 30em of B
47.
(B)
oxidation?
carb
Na' +e - Na
Br +e Br
2S,0 -- S,02 +2eV
46.
If hydrogen io fide is heated in a closed
(C)
vessel to a temperai ire of 425°C and then
maintained at 425°C
2.
carb
(D)
man
carb
Instructions for questions 48-50
Each question in this seciion consists of a statement in the left-hand column followed by a second
statement in the right-hand column. Decide whether each statement is true or false, then if both are true,
hether the second statement is a correet explanatinn of the first Then choose rine response from A to lD
according to the following code:
2.
carb
soith
First Statement Second statement
(A)
)
True
Second statenment is a correct explanation of the first
A
True
statement
Second stateient is NOT tlhe correet esplanation of
the first statenent
True
True
3.
Is
True
False
(A)
D
False
True
(B)
First statement
Second statement
(D)
48.
Reaction cate of a second order Collision frequency increased with
increase
4.
reaction increase with concentration of concentration of reactants.
reactants
Wh
49.
Aniline. C.IINH reacts with ce-
Aniline is a primary aomatie amine
GA)
(C)
5.
cold nitrous acid liberating nitrogen and
forming phenal
Carbon tetruchloride,CCla is a
liquid while lead tetrachloride, PbCla is a increases with increasing atomic number.
solid with higlı melting point
give
abu
50.
In group IV al the Periodie Table metallic character
Pb-
(A)
(C)
6.
(A)
(B)
(C)
(D
hyo
57
9.
Transcribed Image Text:The equilibrium composition of the mixture at 425°C will be independent of the pressure The vessel will coutain hydrogen, iodine and A Which of the following statements about the diagram above are true? When A andB are mixed, there will be an increase in vapour pressure This type of curve could be obtained if A were carbon tetrachloride and B ethanol 3. will have a volume greater than 60 em 1. LAT hydrogen iodide When dynamic equilibrium is attained the composition of the mixture remains constant Which of the following processes represent man 12g A mixture of 30cm of A and 30em of B 47. (B) oxidation? carb Na' +e - Na Br +e Br 2S,0 -- S,02 +2eV 46. If hydrogen io fide is heated in a closed (C) vessel to a temperai ire of 425°C and then maintained at 425°C 2. carb (D) man carb Instructions for questions 48-50 Each question in this seciion consists of a statement in the left-hand column followed by a second statement in the right-hand column. Decide whether each statement is true or false, then if both are true, hether the second statement is a correet explanatinn of the first Then choose rine response from A to lD according to the following code: 2. carb soith First Statement Second statement (A) ) True Second statenment is a correct explanation of the first A True statement Second stateient is NOT tlhe correet esplanation of the first statenent True True 3. Is True False (A) D False True (B) First statement Second statement (D) 48. Reaction cate of a second order Collision frequency increased with increase 4. reaction increase with concentration of concentration of reactants. reactants Wh 49. Aniline. C.IINH reacts with ce- Aniline is a primary aomatie amine GA) (C) 5. cold nitrous acid liberating nitrogen and forming phenal Carbon tetruchloride,CCla is a liquid while lead tetrachloride, PbCla is a increases with increasing atomic number. solid with higlı melting point give abu 50. In group IV al the Periodie Table metallic character Pb- (A) (C) 6. (A) (B) (C) (D hyo 57 9.
The atomic number of an element is:
Number of electrons in á neutral atom
Number of protons in the nucleus
Numerical position of the element in the
39.
(lir).
+41,0a
Ihe reducmg agent is
(A) Mn (B) Ha) Fen (D) Mn0
Which of the following experimental
Periodic Table
35.
The melting points of magnesium oxide
40.
measure the rate of reaction between Cr.0 and (MgO) and barium oxide (BaO) are 3173 K and
MnO)
2Mnt) + 16Hg) + 50,0
techniques may NOT be conveniently used to (MeO) and barium oxide (BaO) are 3173 K and
and
2196 K respectively. This is because:
in acid medium? The cquation is
Tlhe barium ion is a smaller jon than the
magnesium ion
The molar masses of the oxides are different
Magnesium ton has a high charge density
Teading to some covalent character
41.
methylamine dissolves in water
CH,NH, +H,0 =CH,NII + OH-
Base 1 Acid 2 Acid 1 Base 2
CHNH, is Lewis base
OH is a conjugate base of HyO
CH NH/CH NH, is an acul/tbase conjugate
pair
- 2Mn + 10C0,
+ NII,0
(A) Titration (B) Colorimetry
(C) Dilatometry D) Conductimetry
3
Which of the following equilibrium reactions
The equilibrium below is ohtained when
36.
IS NOT affected by a change in pressure?
2NO = N,04tan)
NO + CO =2 Ne + COe
B.
(3)
(C)
N) + 3He) 2NIIe)
(D)
Question 37 and 38 refer to the electronic
Lontigarations below. Nitrogen has five valence
The clements m the series Se to1
Are callea d-block elements
Are all metals of high melting points
Have an incompletely filled 3d suh-shell
42.
electrons.
Consider
the
followng
electron
2.
with the exception of Cu and Zn
The ionization energy of a hydrogen alom is
Energy jump in the Balmer series
Obtained from the line enission spectrum of
2p
43.
11
2.
hydrogen gas
3.
Obtained at the beginaing of the nti
37. Which epresents the grixtmd tate
nitiogen?
44.
Which of the following statenicus apply to
the ethene (CHa) molecuke
The H-C- H bond angles are tetrahedral
Four electrons are involved in bonding in the
(B) (C)
(D)
Which represents the electron arrangement for
N jon?
(A) AB) (C)
21
carbon-carbon bond
It is planar in shape /
38.
3.
(D)
45.
Instructions for questions 39-47 (NINE questions).
In this section, ONE or MORE of the options given
may be correct. Select your answer by means of the
following code.
IL I and 2 only are correct
If 2 and 3 only are correct
I13 only is correct
le avTHD
Transcribed Image Text:The atomic number of an element is: Number of electrons in á neutral atom Number of protons in the nucleus Numerical position of the element in the 39. (lir). +41,0a Ihe reducmg agent is (A) Mn (B) Ha) Fen (D) Mn0 Which of the following experimental Periodic Table 35. The melting points of magnesium oxide 40. measure the rate of reaction between Cr.0 and (MgO) and barium oxide (BaO) are 3173 K and MnO) 2Mnt) + 16Hg) + 50,0 techniques may NOT be conveniently used to (MeO) and barium oxide (BaO) are 3173 K and and 2196 K respectively. This is because: in acid medium? The cquation is Tlhe barium ion is a smaller jon than the magnesium ion The molar masses of the oxides are different Magnesium ton has a high charge density Teading to some covalent character 41. methylamine dissolves in water CH,NH, +H,0 =CH,NII + OH- Base 1 Acid 2 Acid 1 Base 2 CHNH, is Lewis base OH is a conjugate base of HyO CH NH/CH NH, is an acul/tbase conjugate pair - 2Mn + 10C0, + NII,0 (A) Titration (B) Colorimetry (C) Dilatometry D) Conductimetry 3 Which of the following equilibrium reactions The equilibrium below is ohtained when 36. IS NOT affected by a change in pressure? 2NO = N,04tan) NO + CO =2 Ne + COe B. (3) (C) N) + 3He) 2NIIe) (D) Question 37 and 38 refer to the electronic Lontigarations below. Nitrogen has five valence The clements m the series Se to1 Are callea d-block elements Are all metals of high melting points Have an incompletely filled 3d suh-shell 42. electrons. Consider the followng electron 2. with the exception of Cu and Zn The ionization energy of a hydrogen alom is Energy jump in the Balmer series Obtained from the line enission spectrum of 2p 43. 11 2. hydrogen gas 3. Obtained at the beginaing of the nti 37. Which epresents the grixtmd tate nitiogen? 44. Which of the following statenicus apply to the ethene (CHa) molecuke The H-C- H bond angles are tetrahedral Four electrons are involved in bonding in the (B) (C) (D) Which represents the electron arrangement for N jon? (A) AB) (C) 21 carbon-carbon bond It is planar in shape / 38. 3. (D) 45. Instructions for questions 39-47 (NINE questions). In this section, ONE or MORE of the options given may be correct. Select your answer by means of the following code. IL I and 2 only are correct If 2 and 3 only are correct I13 only is correct le avTHD
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