The equilibrium NH3(aq) + H2O(1) →NH4*(aq) + OH (aq) at 25 °C is subjected to a temperature jump which slightly increases the concentration of NH4*(aq) and OH¯(aq). The measured relaxation time is 7.61 ns. The equilibrium constant for the system is 1.78 x 10¬5 at 25 °C, and the equilibrium concentration of NH3(aq) is 0.15 mol dm-3. (a) Calculate the rate constant for the forward step. Just value in 3 sig. fig., normal or exponential format, e.g. type in 1.16E6 meaning 1.16 x 10°, must use capital E here. Choose a kf = unit in the next question, must be in one of those.

Chemistry for Engineering Students
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Publisher:Lawrence S. Brown, Tom Holme
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.35PAE: In the reaction in Exercise 12.33, another trial was carried out. The reaction began with an initial...
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QUESTION 7
The equilibrium NH3(aq) + H20(1) →NH4*(aq) + OH (aq) at 25 °C is subjected to a temperature jump which slightly increases the concentration of
NH4*(aq) and OH (aq).
The measured relaxation time is 7.61 ns.
-3
The equilibrium constant for the system is 1.78 x 10-5
at 25 °C, and the equilibrium concentration of NH3(aq) is 0.15 mol dm
(a) Calculate the rate constant for the forward step.
Just value in 3 sig. fig., normal or exponential format, e.g. type in 1.16E6 meaning 1.16 x 10°, must use capital E here. Choose a
kf=
unit in the next question, must be in one of those.
Transcribed Image Text:QUESTION 7 The equilibrium NH3(aq) + H20(1) →NH4*(aq) + OH (aq) at 25 °C is subjected to a temperature jump which slightly increases the concentration of NH4*(aq) and OH (aq). The measured relaxation time is 7.61 ns. -3 The equilibrium constant for the system is 1.78 x 10-5 at 25 °C, and the equilibrium concentration of NH3(aq) is 0.15 mol dm (a) Calculate the rate constant for the forward step. Just value in 3 sig. fig., normal or exponential format, e.g. type in 1.16E6 meaning 1.16 x 10°, must use capital E here. Choose a kf= unit in the next question, must be in one of those.
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