The following data are for the rearrangement of cyclopropane to propene at 500 °C. (CH)3→CH;CH=CH; [(CH)3 ], M time, min 1.87×10-2 14.0 9.35×10-3 4.68×103 42.0 3.74x10-2 28.0 Hint: It is not necessary to graph these data. (1) The half life observed for this reaction is | min . (2) Based on these data, the rate constant for this | v order reaction is -1 min

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 114QRT
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The following data are for the rearrangement of cyclopropane to propene at 500 °C.
(CH))3 → CH3CH=CH,
(CH)3 ], M
9.35x10-3
28.0
3.74x10-2
1.87×10-2
14.0
4.68×10-3
time, min
42.0
Hint: It is not necessary to graph these data.
(1)
The half life observed for this reaction is
min .
(2)
Based on these data, the rate constant for this
order reaction is
min
-1
Transcribed Image Text:The following data are for the rearrangement of cyclopropane to propene at 500 °C. (CH))3 → CH3CH=CH, (CH)3 ], M 9.35x10-3 28.0 3.74x10-2 1.87×10-2 14.0 4.68×10-3 time, min 42.0 Hint: It is not necessary to graph these data. (1) The half life observed for this reaction is min . (2) Based on these data, the rate constant for this order reaction is min -1
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