The following three-step mechanism has been proposed for the reaction between chlorine and chloroform. Step 1: Cl2 (g) ↔ 2 Cl (g) Step 2: Cl (g) + CHCl3 (g) ↔ HCl (g) + CCl3 (g) Step 3: CCl3 (g) + Cl (g) ↔ CCl4 (g) The numerical values of a few of the rate constants for these steps are: k1 = 4.8 x 103, k-1 = 3.6 x 103, k2 = 1.3 x 10-2, k3 = 2.7 x 102 Give the overall chemical reaction. Derive the rate law and the magnitude of k for the overall reaction.
The following three-step mechanism has been proposed for the reaction between chlorine and chloroform. Step 1: Cl2 (g) ↔ 2 Cl (g) Step 2: Cl (g) + CHCl3 (g) ↔ HCl (g) + CCl3 (g) Step 3: CCl3 (g) + Cl (g) ↔ CCl4 (g) The numerical values of a few of the rate constants for these steps are: k1 = 4.8 x 103, k-1 = 3.6 x 103, k2 = 1.3 x 10-2, k3 = 2.7 x 102 Give the overall chemical reaction. Derive the rate law and the magnitude of k for the overall reaction.
Chapter12: Chemical Kinetics
Section: Chapter Questions
Problem 109CP: The following data were collected in two studies of the reaction 2A+BC+D Time (s) Experiment 1 [A]...
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- The following three-step mechanism has been proposed for the reaction between chlorine and chloroform.
Step 1: Cl2 (g) ↔ 2 Cl (g)
Step 2: Cl (g) + CHCl3 (g) ↔ HCl (g) + CCl3 (g)
Step 3: CCl3 (g) + Cl (g) ↔ CCl4 (g)
The numerical values of a few of the rate constants for these steps are:
k1 = 4.8 x 103, k-1 = 3.6 x 103, k2 = 1.3 x 10-2, k3 = 2.7 x 102
- Give the overall
chemical reaction .
- Derive the rate law and the magnitude of k for the overall reaction.
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