Nitryl chloride (NO2Cl) decomposes to nitrogen dioxide (NO2) and chlorine gas (Cl2) according to the following mechanism:1. 2NO2 Cl(g) ⇌ ClO2(g) + N2 O(g) + ClO(g) (fast, k1 represents the rate constant for the forward reaction and k−1 the rate constant for the reverse reaction)2. N2 O(g) + ClO2(g) ⇌ NO2(g) + NOCl(g) (fast, k2 for the forward reaction, k−2 for the reverse reaction)3. NOCl + ClO ⟶ NO2 + Cl2 (slow, k3 the rate constant for the forward reaction)Determine the overall reaction, write the rate law expression for each elementary reaction, identify any intermediates, and determine the overall rate law expression.
Nitryl chloride (NO2Cl) decomposes to nitrogen dioxide (NO2) and chlorine gas (Cl2) according to the following mechanism:1. 2NO2 Cl(g) ⇌ ClO2(g) + N2 O(g) + ClO(g) (fast, k1 represents the rate constant for the forward reaction and k−1 the rate constant for the reverse reaction)2. N2 O(g) + ClO2(g) ⇌ NO2(g) + NOCl(g) (fast, k2 for the forward reaction, k−2 for the reverse reaction)3. NOCl + ClO ⟶ NO2 + Cl2 (slow, k3 the rate constant for the forward reaction)Determine the overall reaction, write the rate law expression for each elementary reaction, identify any intermediates, and determine the overall rate law expression.
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 71GQ
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Nitryl chloride (NO2Cl) decomposes to nitrogen dioxide (NO2) and chlorine gas (Cl2) according to the following mechanism:
1. 2NO2 Cl(g) ⇌ ClO2(g) + N2 O(g) + ClO(g) (fast, k1 represents the rate constant for the forward reaction and k−1 the rate constant for the reverse reaction)
2. N2 O(g) + ClO2(g) ⇌ NO2(g) + NOCl(g) (fast, k2 for the forward reaction, k−2 for the reverse reaction)
3. NOCl + ClO ⟶ NO2 + Cl2 (slow, k3 the rate constant for the forward reaction)
Determine the overall reaction, write the rate law expression for each elementary reaction, identify any intermediates, and determine the overall rate law expression.
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