The folowing is the molecular orbital diagram showing the energy ordering for the molocular orbitals. Use this diagram to answer the question. • Part A Which of the folowing has the shortest bond lenath? OB, Submit laquat Anawer • Part Which diagram best depicts the highost anergy maiecular orbital where an clactron will be found in a B, ion?

The folowing is the molecular orbital diagram showing the energy ordering for the molocular orbitals. Use this diagram to answer the question. • Part A Which of the folowing has the shortest bond lenath? OB, Submit laquat Anawer • Part Which diagram best depicts the highost anergy maiecular orbital where an clactron will be found in a B, ion?

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter6: Quantum Mechanics And Molecular Structure

Section: Chapter Questions

Problem 5P: Compare the electron density in the 1g and 1u* molecular orbitals for H2+ shown in Figure 6.5 with...

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Compare the electron density in the 1g and 1u* molecular orbitals for H2+ shown in Figure 6.5 with the classical model for bonding for H2+ summarized in Figure 3.22b. Which of these molecular orbitals describes the bond in H2+ ?
Give typed full explanation not a single word hand written otherwise leave it Draw the molecular orbital (MO) electron diagram for OF2.
Draw a picture that shows all three 2p orbitals on one atomand all three 2p orbitals on another atom. (a) Imagine theatoms coming close together to bond. How many s bondscan the two sets of 2p orbitals make with each other? (b) Howmany p bonds can the two sets of 2p orbitals make with eachother? (c) How many antibonding orbitals, and of what type,can be made from the two sets of 2p orbitals?
Use the structure of each of the following molecules or ions, predict a) Number of electron domains. Explain your reasoningb) Hybridization. Explain your reasoningc) Electron geometry. Explain your reasoningd) Molecular geometry. Explain your reasoninge) Polarity - if they will be polar or not. Explain your reasoning.
Which hybirdization(s) can form sigma bonds?
Based on Rhodium’s highest energy level, how many bonds do you think it would be able to formwithout hybridization? Explain.
Discuss the nature of the bonding in the nitrate ion (NO3) . Draw the possible Lewis resonance diagrams for this ion. Use the VSEPR theory to determine the steric number, the hybridization of the central N atom, and the geometry of the ion. Show how the use of resonance structures can be avoided by introducing a de-localized MO. What bond order is predicted by the MO model for the NO bonds in the nitrate ion?
Ozone (O3) has a nonzero dipole moment. In the molecule of O3 , one of the oxygen atoms is directly bonded to the other two, which are not bonded to each other. (a) Based on this information, state which of the following structures are possible for the ozone molecule: symmetric linear, nonsymmetric linear (for example, different OO bond lengths), and bent. (Note: Even an OO bond can have a bond dipole if the two oxygen atoms are bonded to different atoms or if only one of the oxygen atoms is bonded to a third atom.) (b) Use the VSEPR theory to predict which of the structures of part (a) is observed.
Discuss the nature of the bonding in the nitrite ion (NO2) . Draw the possible Lewis resonance diagrams for this ion. Use the VSEPR theory to determine the steric number, the hybridization of the central nitrogen atom, and the geometry of the ion. Show how the use of resonance structures can be avoided by introducing a de-localized MO. What bond order does the MO model predict for the NO bonds in the nitrite ion?
Explain why N22+ is diamagnetic, while O24+, which has the same number of valence electrons, is paramagnetic.
Give the hybridization of each atom (except H) in the solvent dimethylsulfoxide. (Unshared electron pairs are not shown.)
Sketch the molecular orbital and label its type ( or , bonding or antibonding) that would be formed when the following atomic orbitals overlap. Explain your labels. a. b. c. d.