The kinetics of the reaction: I + OCI 2 OI + CI was studied in basic aqueous media by Chia and Connick [ J. Phys. Chem. 63:1518 (1959)]. The initial rate of I disappearance is given below for mixtures of various initial compositions, at 25°C (None of the solutions initially contained OI or Cl ). The rate law can be expressed in the form Initial Initial Initial Initial rate composition of I- (M) composition composition of (moll-L-1s-1) of OCI- (M) OH- (M) 2 × 10-3 1.5 × 10-3 1.00 1.8 × 10-4 4 × 10-3 1.5 × 10-3 1.00 3.6 × 10-4 2 × 10-3 3 × 10-3 2.00 1.8 × 10-4 4 × 10-3 3 × 10-3 1.00 7.2 × 10¬4

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 86IL: The acid-catalyzed iodination of acetone CH3COCH3(aq) + I2(aq) CH3COCH2I(aq) + HI(aq) is a common...
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d) What is the order of total reaction?. Tek satır metin.

e) What is the value of the rate constant?. Tek satır metin.
 
The kinetics of the reaction:
I + OCI 2 OI + CI
was studied in basic aqueous media by Chia and Connick [ J. Phys. Chem. 63:1518 (1959)]. The initial rate of I
disappearance is given below for mixtures of various initial compositions, at 25°C (None of the solutions initially
contained OI or CI ).
The rate law can be expressed in the form
Initial
Initial
Initial
Initial rate
composition
of I- (M)
composition composition of (mol-L-1s-1)
of OCI- (M)
OH- (M)
2 × 10–3
1.5 × 10-3
1.00
1.8 × 10-4
4 × 10-3
1.5 × 10-3
1.00
3.6 × 10-4
2 × 10-3
3 x 10-3
2.00
1.8 x 10-4
4 × 10-3
3 × 10-3
1.00
7.2 x 10-4
Transcribed Image Text:The kinetics of the reaction: I + OCI 2 OI + CI was studied in basic aqueous media by Chia and Connick [ J. Phys. Chem. 63:1518 (1959)]. The initial rate of I disappearance is given below for mixtures of various initial compositions, at 25°C (None of the solutions initially contained OI or CI ). The rate law can be expressed in the form Initial Initial Initial Initial rate composition of I- (M) composition composition of (mol-L-1s-1) of OCI- (M) OH- (M) 2 × 10–3 1.5 × 10-3 1.00 1.8 × 10-4 4 × 10-3 1.5 × 10-3 1.00 3.6 × 10-4 2 × 10-3 3 x 10-3 2.00 1.8 x 10-4 4 × 10-3 3 × 10-3 1.00 7.2 x 10-4
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