The Lewis structure of SF4 has four bonded pairs of electrons and one lone pair. Propose two structures for SF4 based a trigonal bipyramidal coordination at S, and a further structure based on a square pyramid. For each structure, describe the expected form of the 19F NMR spectrum, giving your reasons. Hint: You do not need to consider possible interaction with the S nucleus.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter19: Nuclear Magnetic Resonance Spectroscopy
Section: Chapter Questions
Problem 19.5QAP
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The Lewis structure of SF4 has four bonded pairs of electrons and one lone pair. Propose two structures for SF4 based a trigonal bipyramidal coordination at S, and a further structure based on a square pyramid. For each structure, describe the expected form of the 19F NMR spectrum, giving your reasons. Hint: You do not need to consider possible interaction with the S nucleus.

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