The naphthalene molecule has a structure that corre- sponds to two benzene molecules fused together: H H | H. H H H The 7-electrons in this molecule are delocalized over the entire molecule. The wavelength of maximum absorption in the UV-visible part of the spectrum in benzene is 255 nm. Is the corresponding wavelength shorter or longer than 255 nm for naphthalene?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
Problem 40P
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The naphthalene molecule has a structure that corre-
sponds to two benzene molecules fused together:
H
H
|
H.
H
H
H
The 7-electrons in this molecule are delocalized over the
entire molecule. The wavelength of maximum absorption in
the UV-visible part of the spectrum in benzene is 255 nm.
Is the corresponding wavelength shorter or longer than
255 nm for naphthalene?
Transcribed Image Text:The naphthalene molecule has a structure that corre- sponds to two benzene molecules fused together: H H | H. H H H The 7-electrons in this molecule are delocalized over the entire molecule. The wavelength of maximum absorption in the UV-visible part of the spectrum in benzene is 255 nm. Is the corresponding wavelength shorter or longer than 255 nm for naphthalene?
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