2. Use Figure 7.2 to estimate the approximate wavelength of maximum absorption for an aque- ous solution of each of the following: Hemoglobin (the molecule that gives blood its color) а. nm b. Chlorophyll (the pigment that gives algae their color) nm
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- The absorbance of 10 mL of 0.0005 M Co2+ solution is 0.35. 10 mL of this solution mixed with 10 mL of the sample solution produces an absorption of 0.52. Calculate the concentration of Co2+ in the sampleThe CO stretching vibration frequencies measured in the IR spectra taken in hydrocarbon solutions of co-electron [Mn(CO)6], [Mn(CO)6]- and [Mn(CO)6]+ complexes are 1981, 1859 and 2101 cm-1, respectively. According to these values, the Explain C≡O bond lengths and Mn-C bond lengthsWhat are 2 most unique aspect of NMR, UV spectroscopy , IR spectroscopy, and Mass Spectroscopy
- At 580nm, the wavelength of its maximum absorption, a 3.75 x10^-5 M solution of the complex FeSCN2+ has an absorbance of 0.2734 in a 1.00cm cell. what will be the absorbance of a solution in a 2.0 cm cell with concentraion 1.25* 10-5 concentrationAt 580 nm, the wavelength of its maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of 7.00x103 L mol-1 cm-1. Calculate a.) the absorbance of 2.50x10-5 M solution of the complex at 580 nm in 1.00-cm cell. b.) the absorbance of a solution in which the concentration of the complex is twice that in part (a). c.) the transmittance of the solutions described in parts (a) and (b). d.) the absorbance of a solution that has half the transmittance of that described in part (a).Briefly explain how AAS can quantify the amount of lead in sample solution?
- The CO stretching vibration frequencies measured in the IR spectra taken in hydrocarbon solutions of co-electron [Mn(CO)6], [Mn(CO)6]- and [Mn(CO)6]+ complexes are 1981, 1859 and 2101 cm-1, respectively. According to these values, compare the C≡O bond lengths in the complexes by explaining the Mn-C bond lengths.Identify the first row transition metal that satisfies the requirements given:a. [M(H2O)6]2+ having two unpaired electrons (list all possibilities).b. [M(NH3)6]3+ that may have splitting of spin-allowed absorption band as a consequence of distortion of excited state (provide one example).c. [M(H2O)6]2+ expected to have the palest color in aqueous solution.Consider the octahedral complex [FeBr6] 4−. In water solution it has an absorption peak at 864 nm with a molar absorptivity (ε) of 3.6 L mol-1 cm-1 . (a) What is the energy (in wavenumbers, cm-1 ) of the absorption peak? Show all work
- Calculate the number of Schottky defects per m3 in KCl at 500oC. Energy required for the formation of each Schottky defect is 2.6 eV / atom, the density of KCl at 500oC is 1.995 g / cm3, k = 8.62x10-5eV / K.At 580 nm, the wavelength of its maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of 7.00 X 103 L mol-1 cm-1. Calculate (a) the absorbance of a 2.50 X 10-5 M solution of the complex at 580 nm in a 1.00-cm cell. (b) the absorbance of the solution in which the concentration of the complex is twice that in part (a) (c) the transmittance of the solutions described in parts (a) and (b) (d) the absorbance of a solution that has half the transmittance of that described in part (a) answer letter d pleaseAt 580 nm, the wavelength of its maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of 7.00 X 103 L mol-1 cm-1. Calculate (a) the absorbance of a 2.50 X 10-5 M solution of the complex at 580 nm in a 1.00-cm cell. (b) the absorbance of the solution in which the concentration of the complex is twice that in part (a) (c) the transmittance of the solutions described in parts (a) and (b) (d) the absorbance of a solution that has half the transmittance of that described in part (a)