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- Determine the number of total degrees of freedom and the number of vibrational degrees of freedom for the following molecules. a Hydrogen fluoride, HF b Hydrogen telluride, H2Te c Buckminsterfullerene, C60 d Phenylalanine, C6H5CH2CHNH2COOH e Naphthalene, C10H8 f The linear isomer of the C4 radical g The bent isomer of C4 radical.Which molecules below are rotational Raman active and which are inactive. O3 CH4 NH3 H2 H2O SiH4 CF6 C4H10state which of the following molecules show a pure rational microwave absorption spectrum and explain why (a) H2O (b) CO2 (c) NH3 (d) N2O (e) Benzene (f) Cl2
- Which one of the following molecules have IR-active vibrational modes that are not Raman-active? H2O NH3 CH4 SF6Write down the approximate number of waves that appear on the FTIR spectra for the compounds Cyclohexanol and Butanoate Acid! analyze spectroscopy(Fourier-transform infrared spectroscopy)Three of the term symbols that correspond to a nd2electron configuration are 1S, 3P, and 3 Rank these in terms of increasing energy. 1S < 3F < 3P 3F < 3P < 1S 3P < 3F < 1S 1S < 3P < 3F What is the multiplicity for a state that has two unpaired electrons with parallel spin? 0 1 2 3 What is a selection rule for vibrational (IR) spectroscopy? The angular momentum must change by a value of ±1 (? = ±1) The change in vibrational state is ±1 (? = ±1) The molecule must have a permanent dipole The molecule must be anisotropic
- Beta-carotene is an organic compound with an orange color. The diagram above shows the ultraviolet spectrum of beta-carotene. Which of the following statements is true about the absorption bands in the spectrum?(see attached image) a.) The absorption band between 250250 and 320 nm320 nm is due to transitions in electronic energy levels, and the absorption band between 380 and 520 nm is due to transitions in molecular vibrational levels. b.) The absorption band between 250 and 320 nm is due to transitions in molecular vibrational levels, and the absorption band between 380 and 520 nm is due to transitions in molecular rotational levels. c.) The two main absorption bands are associated with transitions in electronic energy levels. The band in the region corresponding to shorter wavelengths shows a lower absorbance than the band in the region corresponding to longer wavelengths. d.) The two main absorption bands are associated with transitions in molecular vibrational levels.…All of the following are reasons electronic spectra of molecules typically contain broad peaks EXCEPT There are rotational states present (in addition to electronic transitions) There are many states of similar energy for each transition There are vibrational states present (in addition to electronic transitions) All electronic transitions are forbidden and thus have long lifetimesBeta-carotene dye has a strong absorptions in the visible region between 400 and 500 nm, the maximum absorption peak is located at 470 nm. Predict the colour of the dye and explain your answer by providing an appropriate colour wheel chart.
- Match the region of the electromanetic spectrum with the type of chemical spectroscopy. Nuclear magnetic resonance (NMR) - electron and proton resonance Options: X-rays Microwaves Infared Radio waves Ultraviolet and visible light Raman spectroscopy-molecular rotations options: X-rays Microwaves Infared Radio waves Ultraviolet and visible light Electron excitation (energy level changes) Options: X-rays Microwaves Infared Radio waves Ultraviolet and visible light IR spectroscopy - molecular vibrations Options: X-rays Microwaves Infared Radio waves Ultraviolet and visible light Ionization Options: X-rays Microwaves Infared Radio waves Ultraviolet and visible lightHow many normal vibrational modes does each of thefollowing molecules have?(a) NH3(b) C2H4(c) CCl2F2(d) CH3CH2OHAll of the following are TRUE about molecular fluorescence spectroscopy, except: A. the sensitivity is one to three orders of magnitude better than absorption spectroscopy. B. the radiant power of fluorescence is proportional to the radiant power of the excitation beam absorbed. C. small linear concentration range. D. the absorption spectrum and the fluorescence spectrum for a compound often appears as approximate mirror images.