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- A volumetric calcium analysis on triplicate samples of the blood serum of a patient believed to be suffering from a hyperparathyroid condition produced the following data: mmol Ca/L = 3.15, 3.25, 3.26. What is the 95% confidence interval for the mean of the data, assuming no prior information about the precision of the analysis?What are the differences between systematic and random errors and how do they effect accuracy and precision? In what circumstances would you use standard addition (versus a normal calibration curve) to determine the amount of an analyte in a sample? A urine sample, containing analyte Z is analysed by the standard addition method where 5 mL of the original sample was mixed with increasing amounts of a Z standard and each solution diluted to a volume of 50 mL prior to analysis. A plot of the final concentration of the standard in each of the 50 mL samples (x axis) versus The measured signal from the analysis of each 50 mL sample (on y axis) produced a straight line with the general equation: y = 44.72x + 4.06 what was the final concentration of Z in the 50 mL standard addition sample? what was the initial concentration of Z in the original urine sample?What is the absolute uncertainty and relative uncertainty of the molarity of the solution? M = = 0.078376462 = 0.078 M Pb2+
- A stock solution of 0.225 +/- 0.003 M NaNO2 was transferred to a 100 mL volumetric flask (class A) and diluted to the mark. If 7 mL of the stock solution was transferred using one 5-mL and two 1-mL volumetric pipettes, what is the new concentration of the solution and the uncertainty?1. A student performed this experiment and obtained the following concentration values: 0.02813 M, 0.02802, and 0.02788 M a. what is the mean concentration? b. what is the standard deviation of these results? 3. how would the following errors affect the concentration of Cl- obtained in question 2b? give your reasoning in each case. a. the student read the molarity of AgNo3 as 0.02104M instead of 0.02014M b. the student was past the endpoint of titration when he took the final buret reading.A stock solution of 0.225 +/- 0.003 M NaNO2 was transferred to a 100 mL volumetric flask (class A) and diluted to the mark. If 7 mL of the stock solution was transferred using one 5-mL and two 1-mL volumetric pipettes, what is the new concentration of the solution and the uncertainty? Please show how to calculate the uncertainty, that is the one part I don't understand how to do
- An excess of 0.34 mg Pb is obtained from an assay test determined in an analysis. What is the percent relative error in ppt if the mass of the sample is 550 g?1. What is the MW of the analyte?2. What is the meq of the analyte?3. What will be the weight (in grams) of the analyte if the standardization is to be quartered?4. What will be Normality of the solution if 7.5ml of the titrant was consumed in the standardization?5. What is the average Normality if two or more trials were conducted with the values of 0.102N and 0.105N?After creating her standard curve for absorption versus the concentration (M) of FD&C Red 40 and processing her data, Sally found that her drinking strength Kool-Aid sample had a concentration of 4.692 x 10–5 M. If 0.132 grams of Kool-Aid powder was used to prepare an 8-fl oz cup of her assigned flavor, what is the percent by mass of FD&C Red 40 in her Kool-aid powder? Report your answer as a percentage with two places after the decimal. Do not include the percentage sign in your answer. Pay attention to units. You are trying to find the mass percentage of red dye, so you need to know each variable in the equation in Appendix B. Note that the percent by mass equation should be multiplied by 100. There may be some useful conversion factors in the experimental procedure.
- Consider the structure of testosterone to identify the best suitable quantitative analysis for testosterone?Differentiate between qualitative analysis and quantitive analysis?A volumetric calcium analysis on triplicate samples of the blood serum of a patient believed to be suffering from a hyperparathyroid condition produced the following data: mmol Ca/L = 3.55, 3.65, 3.14. What is the 95% confidence interval for the mean of the data, assuming(a) No prior information about the precision of the analysis?(b) s → σ = 0.056 mmol Ca/L?