Phase Transition Thermodynamic DataformulaTm (°C)AH fus (kJ/mol)E (K-kg/mol)T, (°C)ΔΗvap (kJ/mol)Еъ (К-kg/mol)T. (°C)P (atm)C4489117CBrCIF2-3.6153.7342.0CBRF3CB12F2CBr4-57.767.139.225198.240.892.33.76CCIF3-81.32938.2CL,F2CCI3F-29.7111.8040.823.8198.044.1CC14-22.622.5676.829.82283.544.6CF4CHCIF2-127.9-45.536.9-40.696.449.7CHCI,FCHC139.0178.551.1-63.419.561.1729.24263.354.0CHF3-82.026.247.9CH,Cl,CH2F2CH3CNCH;COC,H5CH3CONH,CH;CO,C,H5-97.24.6049.628.062.4223760.2-51.578.557.581.651.44272.548.25.163.922.82CH3CI-97.76.43-24.0921.40143.1065.9CH3F-78.344.758.0CH3I4.31CH;NO4.25CH;NO22.09CH3OH-97.533.21564.635.210.86239.479.8CH4-182.470.94-161.488.19-82.945.4CO-205.020.833-191.56.04-140.234.5COCI,818256.0CO2-56.569.02-78.5031.173.0CS24627978.0C19H160C10H8C12H11N37.87.458.38 Please use the values in the resources listed below instead of the textbook values.The rate of the electron-exchange reaction between naphthalene (C10H8) and its anion radical (C10H8¯) in an organic solvent is diffusion controlled.C10H8 + C10H8=C10H8 + C10H8-The reaction is bimolecular and second order. The rate constants are as follows.T/K305295291275k/109 M-1.s-1 2.64 2.21 2.05 1.49Calculate the values of Ea, AH°†, AS°† and AG°† at 295 K for the reaction. [Hint: Rearrange the equation below and plot In(k/T) versus 1/T.]kBT ASot/Re-AH°ł/RT(M1 – m)k =hEa =17.8X kJ•mol-1AH°# =12.9X kJ•mol-1ASot = |-22.3X J-K-1.mol-1AG°# =19.5kJ•mol-1

The rate of the electron-exchange reaction between naphthalene (C10H8) and its anion radical (C10H8¬) in an organic solvent is diffusion controlled. C10H8¯ + C10H8=C10H8 + C10H8¯ The reaction is bimolecular and second order. The rate constants are as follows. T/K 305 295 291 275 k/109 M-1.s-1 2.64 2.21 2.05 1.49 Calculate the values of Ea, AHo#, ASº† and AGº† at 295 K for the reaction. [Hint: Rearrange the equation below and plot In(k/T) versus 1/T.] k = h kBT Asot/Re-AH®?/RT(M1 – m)

The rate of the electron-exchange reaction between naphthalene (C10H8) and its anion radical (C10H8¬) in an organic solvent is diffusion controlled. C10H8¯ + C10H8=C10H8 + C10H8¯ The reaction is bimolecular and second order. The rate constants are as follows. T/K 305 295 291 275 k/109 M-1.s-1 2.64 2.21 2.05 1.49 Calculate the values of Ea, AHo#, ASº† and AGº† at 295 K for the reaction. [Hint: Rearrange the equation below and plot In(k/T) versus 1/T.] k = h kBT Asot/Re-AH®?/RT(M1 – m)

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter11: Chemical Kinetics: Rates Of Reactions

Section11.3: Rate Law And Order Of Reactions

Problem 11.5PSP

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