The reaction between O2 and hemoglobin in aqueous solution has an experimentally determined overall rate constant k, = 4 x104 dm³ mol-'s-1. The diffusion coefficient for O2 in water is 2.0 x 10-° m² s-1 and the diffusion coefficient for hemoglobin in water is 6.9 x 10-11 m²s1. Use the radius of hemoglobin, 3.1 nm for critical distance R*. Is this reaction diffusion-limited? Justify?

Chemistry for Engineering Students
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Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.33PAE: The following experimental data were obtained for the reaction of \'I14* and NOf in acidic solution....
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The reaction between O2 and hemoglobin in aqueous solution has an experimentally
determined overall rate constant k, = 4 x104 dm³ mol-'s-1. The diffusion coefficient for O2 in water
is 2.0 x 10-° m² s-1 and the diffusion coefficient for hemoglobin in water is 6.9 x 10-11 m²s1. Use
the radius of hemoglobin, 3.1 nm for critical distance R*.
Is this reaction diffusion-limited? Justify?
Transcribed Image Text:The reaction between O2 and hemoglobin in aqueous solution has an experimentally determined overall rate constant k, = 4 x104 dm³ mol-'s-1. The diffusion coefficient for O2 in water is 2.0 x 10-° m² s-1 and the diffusion coefficient for hemoglobin in water is 6.9 x 10-11 m²s1. Use the radius of hemoglobin, 3.1 nm for critical distance R*. Is this reaction diffusion-limited? Justify?
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