The sulfur from 4.00g steel is evolved as dihydrogen sulfide gas and titrated with 1.60 mL of 0.0500N iodine solution. How many milliliters if iodine will be reduced by 40.00 mL of Na2S2O3 solution of which 1mL thiosulfate solution = 0.006354g Cu? H2S + 12 → S + 21- + 2H+ AsO33- + 2HCO3- + l2 → AsO43- + 21- + 2CO2 + H20 2Cu2+ + 41- → 2Cul + l2 103 + 61- + 6H+ → 312 + - 3H2O 4.0mL 2.0mL 80mL O 160mL

The sulfur from 4.00g steel is evolved as dihydrogen sulfide gas and titrated with 1.60 mL of 0.0500N iodine solution. How many milliliters if iodine will be reduced by 40.00 mL of Na2S2O3 solution of which 1mL thiosulfate solution = 0.006354g Cu? H2S + 12 → S + 21- + 2H+ AsO33- + 2HCO3- + l2 → AsO43- + 21- + 2CO2 + H20 2Cu2+ + 41- → 2Cul + l2 103 + 61- + 6H+ → 312 + - 3H2O 4.0mL 2.0mL 80mL O 160mL

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter31: Introduction To Analytical Separations

Section: Chapter Questions

Problem 31.21QAP

See similar textbooks

Similar questions

The SO2 present in air is mainly responsible for the phenomenon of acid rain. The concentration of SO2 can be determined by titrating against a standard permanganate solution as follows: 5SO2 + 2MnO4- + 2H2O ---> 5SO42- + 2Ms2 + 4H+ Calculate the number of grams of SO2 in a sample of air if 4.90mL of 0.00700M KMnO4 solution are required for the titration. Be sure your answer has the correct number of significant digits.
For titration for determination of Chloride, 0.05 AgNO3 and NaCl with a 5% (w/v) K2CrO4 indicator, what is the % (w/w) Cl- using the atomic weight for Chlorine. Data below: Primary standard weight 0.1173g , 0.1056g , and 0.1049g Vol of titrant delivered 35.47mL , 31.75mL, and 31.04mL Uknown Chloride mass 0.1527g, 0.1442g, and 0.1337g Vol of titrant delivered 40.00mL ,37.68mL ,and 34.96 mL
Prepare 1.0 L of a 50.00 ppm iron solution from the solid Fe(NH4)2(SO4)2 of the80.0% purity. Clearly describe how to prepare this solution. If doneChlorimetric iron analysis using the calibration curve method, specify theform of preparation of 100.0 ml of each of the following standard solutions withcontents of 1.00, 5.00, 15.00 and 20.00 ppm of Fe respectively from the solutionmother (It suppose that the answers are: 0.3180, 2.00, 10.00, 20.00, 30.00 and 40.00 ml of the mother solution and dilute exactly to 100.0 mL with deionized water)
Calculate the molarity of the nickel solution. From the following data calculate the normalities of the acid and base solutions: weight of pure Na2CO3 = 0.2448 g; volume of acid = 43.65 mL ; volume of base used in back titration = %3D 0.84 mL ; 1.000 mL of base = 0.982 mL of acid. Reaction: CO, + 2H* → H2CO3
Calcium fluoride is considered as a relatively insoluble compound and therefore lime or slakedlime has been considered as a possible material to remove excess fluoride in water of boreholesin certain parts of the country. The solubility product of CaF2 is Ksp = 3 x 10 – 11 and that ofCa(OH)2 isKsp =8x10-61. How much lime can be added to the water to remove 10 mg of F- ion per litre ofborehole water?(The atomic masses are Ca: 40.08; F: 19.00; O: 16; H: 1)
A 20 ml aliquot of malonic acid solution was treated with 10.0 ml of 0.25M Ce4+ leading to the reaction CH2(COOH)2 + 6Ce4+ + 2H2O ® HCOOH + 2CO2 + 6Ce3+ + 6H+ After standing for 10 minutes at 60oC, the solution was cooled and the x’ss Ce4+ was titrated with 0.1M Fe2+, requiring 14.4 ml to reach the ferroin end point. Calculate the M of the malonic in the sample.
The solubility of borax, which is made up of sodium tetraborate (Na2B4O5(OH)4 8H2O), was analyzed. The dissolution of borax is: Na2B4O5(OH)4 • 8H2O(s) ⇌ 2 Na+(aq) + B4O5(OH)42–(aq) + 8 H2O(l) A 50 mL saturated solution was prepared. After filtration of solution, 5 mL aliquot was transferred to a flask and titrated using 0.432 M HCl. The endpoint was found to be 4.73 mL of the titrant. Tetraborate anion (B4O5(OH)42-) is a weak base which reacts with HCl like the following reaction: B4O5(OH)42–(aq) + 2 H+(aq) + 3 H2O(l) ⇌ 4 H3BO3(aq) What is Ksp expression for the dissolution? What is the tetraborate ions concentration in the filtrate? What is the molar solubility and Ksp of borax if the titration was done at room temperature (298 K)?
Using basic conditions, MnO4- can be used as titrant for the analysis of Mn2+, with both the analyte and the titrant ending up as MnO2. In the analysis of a mineral sample for manganese, a 0.5165-g sample is dissolved, and the manganese is reduced to Mn2+. The solution is made basic and titrated with 0.03358 M KMnO4, requiring 34.88 mL to reach the endpoint. Calculate the %w/w Mn in the mineral sample. Answer: % Mn =
A sample containing calcium was analyzed by gravimetry, converting all calcium to calcium oxalate monohydrate (CaC2O4 • H2O). The sample weighing 0.2654 g was dissolved by adding 6M HCl, and then ammonium oxalate solution was added to precipitate all the calcium. The precipitate was suction filtered and dried in an oven at 95 °C for one hour. The solid obtained weighed 0.3216 grams.Calculate:A) The percentage of CaCO3B) The percentage of Ca C) The percentage of CaO
What is the percentage purity of a sample of impure oxalic acid dihydrate if a sample weighing 0.2003 gram requires 29.30 mL of permanganate solution, of which 1.000 mL ≈ 0.006023 g iron?
1. A newly discovered iron ore was weighted (5.408 g) and worked up to produced 0.3785 g of ignited Fe2O3 precipitate. What is the percent purity of the iron in the sample? 2. Distinguish between equivalence point and end point.
A 0.1093-g sample of impure Na2CO3 was analyzed by the Volhard Method. After adding 50.00 mL of 0.06911 M AgNO3, the sample was back titrated with 0.05781 M KSCN, requiring 27.36 mL to reach the end point. Report the purity of Na2CO3sample.