The van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship between pressure p, volume V and temperature T for gases better than the Ideal Gas Law does: p+ (V-nb)=nRT The van der Waals equation of state. R stands for the gas constant and n for moles of gas. The parameters a and b must be determined for each gas from experimental data. Use the van der Waals equation to answer the questions in the table below. What are the units of a? What are the units of b? For water the numerical value of a is 5.464 and the numerical value of b is 0.0305. atm Use the van der Waals equation to calculate the pressure of a sample of water at 445.0 °C with a molar volume of 0.366 L/mol. Round your answer to 3 significant digits.

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Chapter5: The Gaseous State
Section: Chapter Questions
Problem 5.103QP: Calculate the molar volume of ethane at 1.00 atm and 0C and at 10.0 atm and 0C, using the van der...
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Use the Ideal Gas Law to calculate the pressure of the same
sample under the same conditions. Round this answer to 3
significant digits also.
atm
Transcribed Image Text:Use the Ideal Gas Law to calculate the pressure of the same sample under the same conditions. Round this answer to 3 significant digits also. atm
The van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship between pressure p, volume V and
temperature T for gases better than the Ideal Gas Law does:
p+a
(V-пb) —пRT
The van der Waals equation of state. R stands for the gas constant and n for moles of gas.
v²
The parameters a and b must be determined for each gas from experimental data.
Use the van der Waals equation to answer the questions in the table below.
x10
What are the units of a?
What are the units of b?
For water the numerical value of a is 5.464 and the numerical
value of b is 0.0305.
atm
Use the van der Waals equation to calculate the pressure of a
sample of water at 445.0 °C with a molar volume of 0.366 L/mol.
Round your answer to 3 significant digits.
Transcribed Image Text:The van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to predict the relationship between pressure p, volume V and temperature T for gases better than the Ideal Gas Law does: p+a (V-пb) —пRT The van der Waals equation of state. R stands for the gas constant and n for moles of gas. v² The parameters a and b must be determined for each gas from experimental data. Use the van der Waals equation to answer the questions in the table below. x10 What are the units of a? What are the units of b? For water the numerical value of a is 5.464 and the numerical value of b is 0.0305. atm Use the van der Waals equation to calculate the pressure of a sample of water at 445.0 °C with a molar volume of 0.366 L/mol. Round your answer to 3 significant digits.
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