This compound can be synthesized from compounds (A) and (B).Propose a synthesis of compound (A) from toluene.NH₂dio-88BrBr-a. CH3CH=CH₂, H3PO4b. acetyl chloride, AlCl3c. HNO3/H₂SO4d. 2-methylpropanoyl chloride, AlCl3e. H₂, Pd/Cf. BH3/THFFrom the table of reagents, select the components necessary to synthesize the given molecule and enter their letters, in the order that they areto be used without commas between, in the box, i.e. 'hiacc'.If a reaction is to be used more than once, enter its letter multiple times as necessary.Reagents Availableg. H₂NNH₂, OH, H₂Oh. OHi. CH31(A)j.H₂CRO4k. Br₂, FeBr3I. SOCI₂OHm. Cl₂, FeCl3n. Cl2₂, Ao. propanoyl chloride, AICI 3p. Br₂, H+q. t-butylamineNO₂(B)CI

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Answered: This compound can be synthesized from…

This compound can be synthesized from compounds (A) and (B). Propose a synthesis of compound (A) from toluene. NH₂ 09-08 Br Br (A) OH NO₂ (B) CI

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter16: Aldehydes And Ketones

Section: Chapter Questions

Problem 16.60P

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Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

This compound can be synthesized from compounds (A) and (B).
Propose a synthesis of compound (A) from toluene.
NH₂
dio-88
Br
Br-
a. CH3CH=CH₂, H3PO4
b. acetyl chloride, AlCl3
c. HNO3/H₂SO4
d. 2-methylpropanoyl chloride, AlCl3
e. H₂, Pd/C
f. BH3/THF
From the table of reagents, select the components necessary to synthesize the given molecule and enter their letters, in the order that they are
to be used without commas between, in the box, i.e. 'hiacc'.
If a reaction is to be used more than once, enter its letter multiple times as necessary.
Reagents Available
g. H₂NNH₂, OH, H₂O
h. OH
i. CH31
(A)
j.
H₂CRO4
k. Br₂, FeBr3
I. SOCI₂
OH
m. Cl₂, FeCl3
n. Cl2₂, A
o. propanoyl chloride, AICI 3
p. Br₂, H+
q. t-butylamine
NO₂
(B)
CI

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