This problem uses a bicarbonate/carbonate buffer which means that we can consider the following equilibrium showing bicarbonate acting as a Brønsted acid: HCO3-    +      H2O    ⇌      CO32-     +      H+ Verify that the Ka for bicarbonate is 4.7 x 10-11 and show that the pKa is 10.3 Write the appropriate Ka expression for the above equilibrium as well as the corresponding Henderson-Hasselbach equation.

Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter8: Polyfunctional Acids And Bases
Section: Chapter Questions
Problem 3P
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This problem uses a bicarbonate/carbonate buffer which means that we can consider the following equilibrium showing bicarbonate acting as a Brønsted acid:

HCO3-    +      H2O    ⇌      CO32-     +      H+

Verify that the Ka for bicarbonate is 4.7 x 10-11 and show that the pKa is 10.3 Write the appropriate Ka expression for the above equilibrium as well as the corresponding Henderson-Hasselbach equation. 

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