To which orbitals may electrons in a 3p orbital make spectroscopic transitions in a hydrogenic atom?

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter9: Pre-quantum Mechanics
Section: Chapter Questions
Problem 9.48E
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To which orbitals may electrons in a 3p orbital make spectroscopic transitions in a hydrogenic atom?

Expert Solution
Step 1

The promotion of an electron from lower energy orbital to higher energy orbital is termed as electronic transitions.

Step 2

An electron in 3p orbital can have electronic transitions either in 3d and 4f orbitals.

The direct transition from 3p to 4f is not allowed because of forbidden symmetry.

Thus,  3p3d4f is allowed.

 

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