Toxic Cr(VI) can be precipitated from an aqueous solution by bubbling SO2 through the solution. How much SO2 is required to treat 3.00 x 10° Lof 5.00x102 mMCr(VI)? 2Cro + 3S0, + 4H* Cr (SO,),+2H,0 2C:0- Cr,(SO,)3 + 2H,0 kg
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- An aqueous waste stream that has a maximum concentrationof 0.50 M H₂SO₄ (d=1.030 g/mL at 25C) will be neutralized by controlled addition of 40% caustic soda (NaOH; d=1.430 g/L) before it goes to the process sewer and then to the chemical plant waste treatment facility. However, a safety re-view finds that the waste stream could meet a small stream of animmiscible organic compound, which could form a flammable vapor in air at 40.°C. The maximum temperature of the causticsoda and the waste stream is 31°C. Could the temperature in-crease due to the heat of neutralization cause the vapor to ex-plode? Assume the specific heat capacity of each solution is 4.184 J/gK.A powdered crude sample of Na2CO3 containing only inert impurities is to be determined by reacting 225.0 mg of the crude sample to 10.0 mL of 3.00 M HCl solution, and bubbling the resulting CO2(g) product in water that is at exactly 29 °C. After the reaction has completed, the level of the liquid inside the eudiometer rests 4.30 cm above the water level in the beaker. The graduation on the eudiometer indicates that the trapped gas is 44.37 mL. The experiment was done under a barometric pressure of 755.2 torr.What is the %purity of the sample to the nearest whole number?One litre of a saturated aqueous solution of Ag2SO4 (MW = 311.79 g mol- 1) at 25 °C is evaporated to dryness. 4.844 g of Ag2SO4 residue was produced. What is the solubility product (Ksp)?
- What is the concentration of ions in the soil solution after fertilizer application? Suppose that 122 pounds of K+ were applied per acre, then a gentle rain soaked the top 10 inches of soil to field capacity, which for the given soil was about 16% water by volume. If the K+ was applied as KCl, it is plausible that it all dissolved and distributed relatively uniformly with the infiltrating water. If so, then what was the K+ concentration in the soil solution in mol K+/L solution? Note that the volume can be computed like we do for an acre-furrow-slice (AFS), as area times depth. This is going to be a relatively small number, so please report your answer in mol K+/L solution to at least 5 decimal places.Gravimetric analysis of Fe3O4 (MW = 232 g/mole) may be undertaken with the following reactions: Fe3O4 → Fe2O3 → Fe (OH)3. Weight of sample containing 8.00% Fe3O4 that must be taken to obtain a precipitate of Fe(OH)3 (MW = 107 g/mole) that weighs 150 mg is . a. 0.108 g b. 0.325 g c. 1.355 g d. 4.065 g Amount of Fe2O3 (MW = 160 g/mole) from which 150 mg of Fe(OH)3 (MW = 107 g/mole) may be obtained is . a. 0.112 g b. 0.224 g c. 0.448 g d. none of the other choices0.1724g of a mineral containing MnO₂ was dissolved and then treated with excess iodide according to the following unbalanced reaction: MnO2(s) + H+ → Mn²+ + I2 + H₂O The I₂ released was titrated with a solution of Na₂S2O3 0.07320 mol/L, requiring 14.65 mL to reach the point end of degree a) Determine the percentage of MnO₂ in the ore. b) When iodine solutions are used as titrants these are prepared by dissolving 1₂ in concentrated KI. Explain the reason for the need for KI in the preparation of these solutions?
- Sample: Commercial bleach Technical specifications:- Composition: sodium hypochlorite (NaClO) and demineralized water;- Active chlorine content: 2.00 to 2.50% (m/m);- Active ingredient: sodium hypochlorite (NaClO).- Approximate density: 1.08 g/ml;- Physical Aspect: Liquid;- Color: Colorless. Note: the active chlorine content refers to the chlorine gas produced from the following reaction:ClO¯ + Cl¯ + 2H+ ⇋ Cl₂(g) + H₂OData:M.A.: H = 1.0079 g/mol; Na = 22.989769 g/mol; S = 32.065 g/mol; I = 126.90447 g/mol; O = 15.9994 g/mol; Cl = 35.453 g/mol. Material available in the laboratory's warehouse: Reagents:Distilled water; standardized solution of sodium thiosulfate (Na₂S₂O₃), at a concentration of 0.0500 mols/L; 20% KI solution; glacial acetic acid and; starch gum (indicator). Glassware:Bechers of all sizes available on the market; 50, 100, 150, 200 and 250 ml Erlenmeyer flasks; 10.00 and 25.00 mL volumetric pipettes; 25.00 mL burette; 25.00, 50.00 and 100.0 mL volumetric flasks. Calculate…TOPIC: GRAVIMETRY SHOW THE SOLUTION The mercury in a 0.7152-g sample was precipitated with an excess of paraperiodic acid, H5IO6, according to the following reactions:5 Hg+2 + 2 H5IO6 ---> Hg5(IO6)2(s) + 10 H+The precipitate was filtered, washed free of precipitating agent, dried and found to weigh 0.3408-g. Calculate the percentage of Hg2Cl2 in the sample. Molar Masses: Hg5(IO6)2 = 1448.75 Hg2Cl2 = 472.09 Answer: 38.82% Hg2Cl2 An iron ore was analyzed by dissolving a 1.1324-g sample in concentrated HCl. The resulting solution was diluted with water, and the iron (III) was precipitated as the hydrous oxide Fe2O3·xH20 by the addition of NH3. After filtration and washing, the residue was ignited at a high temperature to give 0.5394 g of pure Fe2O3. Calculate (a) % Fe, and (b) % Fe3O4 in the sampleMolar Masses: Fe2O3 = 159.69 Fe = 55.847 Fe3O4 = 231.54 Answer: 33.32% Fe and 46.04% Fe3O4The solubility of borax, which is made up of sodium tetraborate (Na2B4O5(OH)4 8H2O), was analyzed. The dissolution of borax is: Na2B4O5(OH)4 • 8H2O(s) ⇌ 2 Na+(aq) + B4O5(OH)42–(aq) + 8 H2O(l) A 50 mL saturated solution was prepared. After filtration of solution, 5 mL aliquot was transferred to a flask and titrated using 0.432 M HCl. The endpoint was found to be 4.73 mL of the titrant. Tetraborate anion (B4O5(OH)42-) is a weak base which reacts with HCl like the following reaction: B4O5(OH)42–(aq) + 2 H+(aq) + 3 H2O(l) ⇌ 4 H3BO3(aq) What is Ksp expression for the dissolution? What is the tetraborate ions concentration in the filtrate? What is the molar solubility and Ksp of borax if the titration was done at room temperature (298 K)?
- Potassium dichromate has several industrial applications. To determine the purity of the salt that will be used in different industrial processes, a sample mass equal to 2.660 g was dissolved and quantitatively transferred to a 500.00 mL flask. An aliquot of 25.00 mL of this solution was treated with excess KI and the released iodine was titrated with 0.1000 mol L-1 sodium thiosulfate, spending 27.00 mL. Calculate the purity of the analyzed salt. Data:K = 39.10 O = 16.00 Cr = 52.00 I = 126.9 S = 32.071) Commercial fuming Sulphuric acid (Oleum-H2S2O6) is 99.9% solution. Please convert it into molarity.2) Find out the Volume (dm3) of product (gas) at RTP when 0.58 M, 150 mL NaOH (aq.) reacts with 350 mL, 0.25 NH4Cl.In a lab, you diluted a sample of bleach to 1/10 concentration in a 250 vol. flask. Then quantitatively transferred into into a beaker and titrated it with a standard sodium thiosulfate solution with a molarity of 0.1215M. You repeated this 3 times. The data below is the amount of sodium thiosulfate that was titrated in the 3 runs. Calculate the molarity in each run of the diluted bleach and the concentration of undiluted bleach sample.
