Two different compounds have the formulation CoBr(SO4)·5NH3. Compound A is dark violet, and compound B is red-violet. When compound A is treated withAgNO3(aq), no reaction occurs, whereas compound B reacts with AgNO3(aq) to form a white precipitate. When compound A is treated with BaCl2(aq), a white precipitate is formed, whereas compound B has no reaction with BaCl2(aq). Answer the following questions: a. Is Co in the same oxidation state in these complexes? Explain the reactivity of compounds A and B with AgNO3(aq) and BaCl2(aq). b. Are compounds A and B isomers of one another? If so, which category from isomers best describes the isomerism observed for these complexes? c. Would compounds A and B be expected to be strong electrolytes, weak electrolytes,

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter19: Complex Ions
Section: Chapter Questions
Problem 4QAP: Platinum(II) forms many complexes, among them those with the following ligands. Give the formula and...
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Two different compounds have the formulation CoBr(SO4)·5NH3. Compound A is dark violet, and compound B is red-violet. When compound A is treated withAgNO3(aq), no reaction occurs, whereas compound B reacts with AgNO3(aq) to form a white precipitate. When compound A is treated with BaCl2(aq), a white precipitate is formed, whereas compound B has no reaction with BaCl2(aq).  

Answer the following questions:

a. Is Co in the same oxidation state in these complexes? Explain the reactivity of compounds A and B with AgNO3(aq) and BaCl2(aq).

b. Are compounds A and B isomers of one another? If so, which category from isomers best describes the isomerism observed for these complexes?

c. Would compounds A and B be expected to be strong electrolytes, weak electrolytes, or nonelectrolytes?

 

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