uonpga SULMOIOI au 10 Meo DMSO heat view structure Part 2 out of 2 ow consider the stereochemistry in the reaction below: Hb Meo DMSO heat lect the answer choice below that correctly picks the appropriate hydrogen to remove in this reaction well as the correct reasoning for this choice. Hb is removed because it is syn-periplanar to the leaving group Cl Hb is removed because it is anti-periplanar to the leaving group Cl Ha is removed because it is syn-periplanar to the leaving group Cl Ha is removed because it is anti-periplanar to the leaving group Cl It doesn't matter whether Ha or Hb is removed as both will lead to the specified product. Hint Solution

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 14MP: Plastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside...
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sm Review & Carbocation Rearrangements
Saved
Part 1:
Predict the product of the following reaction.
Meo
DMSO
heat
view structure
Part 2 out of 2
Now consider the stereochemistry in the reaction below:
Ha
Hb
Meo
DMSO
heat
Select the answer choice below that correctly picks the appropriate hydrogen to remove in this reaction
as well as the correct reasoning for this choice.
Hb is removed because it is syn-periplanar to the leaving group Cl
Hb is removed because it is anti-periplanar to the leaving group C1
Ha is removed because it is syn-periplanar to the leaving group Cl
Ha is removed because it is anti-periplanar to the leaving group Cl
Hint
It doesn't matter whether Ha or Hb is removed as both will lead to the specified product.
Solution
Transcribed Image Text:sm Review & Carbocation Rearrangements Saved Part 1: Predict the product of the following reaction. Meo DMSO heat view structure Part 2 out of 2 Now consider the stereochemistry in the reaction below: Ha Hb Meo DMSO heat Select the answer choice below that correctly picks the appropriate hydrogen to remove in this reaction as well as the correct reasoning for this choice. Hb is removed because it is syn-periplanar to the leaving group Cl Hb is removed because it is anti-periplanar to the leaving group C1 Ha is removed because it is syn-periplanar to the leaving group Cl Ha is removed because it is anti-periplanar to the leaving group Cl Hint It doesn't matter whether Ha or Hb is removed as both will lead to the specified product. Solution
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