UPDATED STRUCTURES 7. Consider the reacion below that gives the two products indicated. A) Indicate which is formed as the major product at high temperature (thermodynamic control) - use the label THERMO and which is formed as the major product at low temperature (kinetic control) - use the label KINETIC B) Show the complete arrow-pushing mechanism for the formation of either product. Show all of the resonance structures of the resonance- stabilized intermediate in the reaction, including amows to move to each new resonance structure. C) Sketch an orbital overlap diagram for the p-orbitals of the resonance-stabilized INTERMEDIATE. You may show sigma bonds as lines. Show the hydrogen atoms. D) Provide a reaction-energy diagram to show the relative energies ot the reactants, products, intermediates, and transition states. (Note: You may ignore chirality) HBr

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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9:31 O w D X MM •
O N a 100%
UPDATED STRUCTURES
7. Consider the reacion below that gives the two products indicated.
A) Indicate which is formed as the major product at high temperature (thermodynamic control) – use the label THERMO
and which is formed as the major product at low temperature (kinetic control) - use the label KINETIC
B)
Show the complete arrow-pushing mechanism for the formation of either product. Show all of the resonance structures of the resonance-
stabilized intermediate in the reaction, including amows to move to each new resonance structure.
C) Sketch an orbital overlap diagram for the p-orbitals of the resonance-stabilized INTERMEDIATE. You may show sigma bonds as lines.
Show the hydrogen atoms.
D) Provide a reaction-energy diagram to show the relative energies of the reactants, products, intermediates, and transition states.
(Note: You may ignore chirality)
Transcribed Image Text:9:31 O w D X MM • O N a 100% UPDATED STRUCTURES 7. Consider the reacion below that gives the two products indicated. A) Indicate which is formed as the major product at high temperature (thermodynamic control) – use the label THERMO and which is formed as the major product at low temperature (kinetic control) - use the label KINETIC B) Show the complete arrow-pushing mechanism for the formation of either product. Show all of the resonance structures of the resonance- stabilized intermediate in the reaction, including amows to move to each new resonance structure. C) Sketch an orbital overlap diagram for the p-orbitals of the resonance-stabilized INTERMEDIATE. You may show sigma bonds as lines. Show the hydrogen atoms. D) Provide a reaction-energy diagram to show the relative energies of the reactants, products, intermediates, and transition states. (Note: You may ignore chirality)
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