Use the following atomic masses (in g/mol): Ca = 40.08; C = 12.01; O = 16; Na = 23; Cl = 35.45 1.) Calculate the CaCO3 content of a chalk sample weighing 0.2545g, consuming 16.67mL of 0.1150M Disodium EDTA in titration.

Use the following atomic masses (in g/mol): Ca = 40.08; C = 12.01; O = 16; Na = 23; Cl = 35.45 1.) Calculate the CaCO3 content of a chalk sample weighing 0.2545g, consuming 16.67mL of 0.1150M Disodium EDTA in titration.

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter17: Complexation And Precipitation Reactions And Titrations

Section: Chapter Questions

Problem 17.20QAP

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An antacid tablet, weighing 1.25 g, was dissolved in a 1.0 L volumetric flask to allow for determination of calcium carbonate and magnesium carbonate contents. After preparing the solution, an aliquot of 10.0 ml was transferred to an Erlenmeyer flask containing a buffer solution with pH = 10. This aliquot was then titrated with EDTA 0.0040 mol/L and the average volume spent was 15.01 mL. To measure calcium after precipitation After the magnesium was fractionated, a second 10.00 mL aliquot of the stock solution was transferred to an Erlenmeyer flask. and the pH of the present solution was adjusted to a value of approximately 13. In EDTA titration, the volume consumed for observation of the end point was equal to 13.03 mL. Based on this information, (a) Outline the two steps involved, representing the related reactions. (b) Calculate the concentrations of CaCO3 and MgCO3 present in the initial solution. (c) Calculate the masses of CaCO3 and MgCO3 present in the pellet. (d) Calculate the…
. An antacid tablet, weighing 1.25 g, was dissolved in a 1.0 L volumetric flask to allow for determination of calcium carbonate and magnesium carbonate contents. After preparing the solution, an aliquot of 10.0 ml was transferred to an Erlenmeyer flask containing a buffer solution with pH = 10. This aliquot was then titrated with EDTA 0.0040 mol/L and the average volume spent was 15.01 mL. To measure calcium after precipitation. After the magnesium was fractionated, a second 10.00 mL aliquot of the stock solution was transferred to an Erlenmeyer flask, and the pH of the present solution was adjusted to a value of approximately 13. In EDTA titration, the volume consumed for observation of the end point was equal to 13.03 mL. Based on this information, a) Outline the two steps involved, representing the related reactions./5 b) Calculate the concentrations of CaCO3 and MgCO3 present in the initial solution./6 c) Calculate the masses of CaCO3 and MgCO3 present in the pellet./6 d) Calculate…
A 0.9352g sample of ore containing Fe³+, Al³+ and Sr²+ was dissolved and made up to 500.00 mL. The analysis of metals was performed using complexation volumetry. Initially, an aliquot of 50.00 mL had its pH adjusted to 1.0 and titrated with a standard 0.03145 mol/L EDTA solution, requiring 6.95 mL to reach the end point. Subsequently, another 25.00 mL aliquot was buffered at pH=5 and titrated with the same EDTA solution, requiring 6.24 mL to reach the end point. Finally, a third aliquot of 25.00 mL was titrated at pH=11, requiring 11.10 mL of the same EDTA solution to complete the titration. Given the molar masses: Fe=55.845 g/mol; Al-26.982 g/mol and Sr-87.620 g/mol. a) Determine the percentage of each of the metals in the sample. b) Explain why the change in pH allows the determination of the three ions in this sample.
Ammonium iron(II) sulfate crystals have the following formula: (NH4)2SO4.FeSO4.nH2O . In an experiment to determine n 8.492g of the salt were dissolved and made up to 250cm^-3 of solution with distilled water and sulphuric acid. A 25.0cm^-3 portion of the solution was titrated against 0.0150 mol dm^-3 KMnO4. A volume of 22.5cm^-3 was required. Find the value of n
3. An antacid tablet, weighing 1.25 g, was dissolved in a 1.0 L volumetric flask to allow for determination of calcium carbonate and magnesium carbonate contents. After preparing the solution, an aliquot of 10.0 ml was transferred to an Erlenmeyer flask containing a buffer solution with pH = 10. This aliquot was then titrated with EDTA 0.0040 mol/L and the average volume spent was 15.01 mL. To measure calcium after precipitation. After the magnesium was fractionated, a second 10.00 mL aliquot of the stock solution was transferred to an Erlenmeyer flask, and the pH of the present solution was adjusted to a value of approximately 13. In EDTA titration, the volume consumed for observation ofthe end point was equal to 13.03 mL. Based on this information,a) Outline the two steps involved, representing the related reactions./5b) Calculate the concentrations of CaCO3 and MgCO3 present in the initialsolution./6c) Calculate the masses of CaCO3 and MgCO3 present in the pellet./6d) Calculate the…
USE THE DATA BELOW ON MOLAR ABSORPTIVITIES FOR THE TWO PRINCIPAL SPECIES IN A SOLUTION OF POTASSIUM DICHROMATE. Four solutions were prepared by dissolving 3.50 x 10^-4 , 3.00 x 10^-4, 2.50 x 10^-4, and 2.00 x 10^-4 moles of K2Cr2O7 in water and diluting to 1.0 L with a pH of 5.55 buffer. Derive theoretical absorbance values using a 1.00-cm cells for each solution and plot the data for (a) 345 nm (b) 370 nm, and (c) 400 nm.
A 2.559 g sample containing both Fe and V was dissolved under conditions that converted the elements to Fe(III) and V(V). The solution was diluted to 500.0 mL and a 50.0 mL aliquot was passed through a Walden 4+ reductor and titrated with 17.74 mL of 0.100 M Ce . A second 50.0 mL aliquot was passed through a Jones reductor and required 44.67 mL of the same Ce4+ solution to reach an endpoint. Calculate the percentage of Fe2O3 and V2O5 in the sample.
Titration of a 25.00 mL sample of mineral water (containing both Ca2+ and Mg2+) at pH 10 required 19.18 mL of 0.01125M EDTA solution. Another 25.00 mL aliquot of the same mineral water was rendered strongly alkaline to precipitate the magnesium. Titration with a calcium-specific indicator required 14.92 mL of the EDTA solution. Calculate the mass of MgCO3 (FW= 84.314 g/mol) in the mineral water in mg (keep 2 decimals).
Use the following atomic masses (in g/mol): Mg = 24.31; H = 1; S = 32.06; O = 16; Na = 23; Cl = 35. 45; Ca = 40.08; C = 12.01; N = 14.01; Mg = 24.31 6.Calculate the magnesium oxide content of 12.35 g Magnesia Magma, which has been dissolved in 50 mL of 1.0340 N H2SO4 and required 24.6 mL of 1.1255 N NaOH in the back titration.
Use the following atomic masses (in g/mol): Mg = 24.31; O = 16; Ca = 40.08; C = 12.01; Na = 23; H = 1; N = 14.01; S = 32.06; Cl = 35.45; 1.) Calculate the MgO content of 12.35g Magnesia Magma, which has been dissolved in 50mL of 1.0340N H2SO4 and required 24.6mL of 1.1255N NaOH in the back titration.
Calculate the mass of disodium EDTA (FW 372.25) needed to make 500-mL 0.015 M solution of EDTA. What is the equilibrium concentration of Y4- if the pH is (1) 7.00, and (2) 9.00?
A 0.7352g sample of ore containing Fe3+, Al3+ and Sr2+ was dissolved and made up to 500.00 mL. The analysis of metals was performed by a chemistry using complexation volumetry. Initially, an aliquot of 50.00 mL had its pH adjusted to 1.0 and titrated with a standard solution of EDTA 0.02145 mol/L, requiring 6.95 mL to reach the end point. Subsequently, another 25.00 mL aliquot was buffered at pH=5 and titrated with the same EDTA solution, requiring 6.24 mL to reach the end point. Finally, a third aliquot of 25.00 mL was titrated at pH=11, requiring 11.10 mL of the same EDTA solution to complete the titration. Determine the percentage of each of the metals in the sample Given the molar masses: Fe=55.845 g/mol; Al=26.982 g/mol and Sr=87.620 g/mol.