What irreducible representations do the four H1s orbitals of CH4 span? Are there s and p orbitals of the central C atom that may form molecular orbitals with them? In SiH4, where 3d orbitals might be available, could these orbitals play a role in forming molecular orbitals by overlapping with the H1s orbitals?

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter12: The Solid State
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Problem 19PS: Considering only the molecular orbitals formed by combinations of the 2s atomic orbitals, how many...
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What irreducible representations do the four H1s orbitals of CH4 span? Are there s and p orbitals of the central C atom that may form molecular orbitals with them? In SiH4, where 3d orbitals might be available, could these orbitals play a role in forming molecular orbitals by overlapping with the H1s orbitals?

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