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- Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.Determine the point group of the following molecules. a cis1,2 Dichloroethylene b trans1,2 Dichloroethylene c Toluene, C6H5CH3 d 1,3-Cyclohexadiene.Structural isomers can have very different point groups. There are three isomers of dichlorobenzene. Identify the point groups of the three isomers.
- Identify the symmetry elements present in the following objects. a The Eiffel Tower. You may have to look up a picture of it if you dont remember its shape b Any book ignore the printing. c An octagonal wood block. d A jack from the set of jacks pictured here: Note that some of the points end differently.Identify the symmetry elements present in the following objects. a A ream of blank paper, no holes. b A ream of blank three-holed paper. c A round pencil, unsharpened, with cylindrical eraser. d A round pencil, sharpened, with cylindrical eraser.Figure 13.27 shows the structure of the molecule porphine. Figure 13.27 The structure of porphine. Determine the symmetry elements present in the molecule, and its point group. Does the point group change if an Fe2+ ion is substituted for the two hydrogen atoms in the center of the porphine ring?
- Determine if the following species have permanent dipole moments. a Dichloromethane, CH2Cl2 b Chlorobenzene, C6H5Cl c Ammonia, NH3 d Carbon dioxide, CO2.a In the Td point group, an S41 improper rotation is equivalent to what other improper rotation? b In the D6h point group, the symmetry operation labeled C21 is equivalent to what other symmetry operation?In your own words, explain why an object that has more symmetry elements is said to have higher symmetry than an object with fewer symmetry elements.
- Make sketches of the following showing approximately correct geometry and all valence shell electrons. Identify all symmetry elements present and determine the point group for the species (d) SO32-. (e)SF6 (f) IF5 (g) CIF3 (h) SO3 (i) CIO2- j) NSF this is the next sub part, A B and C is already answered.What do you expect the structure of Ge2H4 to look like ? sketch the structure in a clear three dimensional representation and give it's point group.Make sketches of the following showing approximately correct geometry and all valence shell electrons. Identify all symmetry elements present and determine the point group for the species (a) OCN -, (b) IF2+ (c) ICI4-. (d) SO32-. (e)SF6 (f) IF5 (g) CIF3 (h) SO3 (i) CIO2- j) NSF