What is the major organic product formed in the following reaction? C2H5 Ph C,H;ONa CH3 C2H5 Ph C2H5 Ph (A) (В) CH3 OC2H5 Hi CH3 C2H5 C2H5 H Ph CH3 Ph Ph (C) (D) OC2H5 OC,H5 C2H5 H. H.
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- The alcohol compound güven the formula below iş used in perfume making. Bromine benzeme and -1 synthesis of this compound using the necessary organı and indir chemicals showThe oxygen in water is primarily (99.8%) 16O, but water enriched with theheavy isotope 18O is also available. When a ketone or aldehyde is dissolved inH2O, the isotopic label becomes incorporated into the carbonyl group: R2CPO H2O n R2CPO H2O. Explain.The analgesic acetaminophen is synthesized by treating 4-aminophenol with one equivalent of acetic anhydride. Complete the equation for the formation of acetaminophen. a. Acetaminophen: b. Additional Product pls add the name for both, thanks!
- To prepare butanoic acid from 1-propanol, which sequence of reagent(s) is/are best employed? a) (1) NaCN; (2) H2O; (3) [H+] b) LiAlH4 c) K2Cr2O7 in acid d) (1) PBr3; (2) NaCN; (3) H2O; (4) [H+]Complete the reaction: 42K19 → + β + [a]_____________Compounds A, B, and C have the same molecular formula C4H8. They all react wotu H2/PtO2 to give the same compound. The reaction of A or B with H2O/H2SO4 or with BH3-THF, followed by treatment with a basic solution of hydrogen peroxide, gives the same compound, namely D. The reaction of C with H2O/H2SO4 also gives D. However, the reaction of C with BH3-THF, followed by HO-, H2O2 gives a new compound, E. Provide the identity of A, B, C, D, and E along with explanations of reactivity.
- As far back as the 16th century, South American Incas chewed the leaves of the coca bush, Erythroxylon coca, to combat fatigue. Chemical studies of Erythroxylon coca by Friedrich Wöhler in 1862 resulted in the discovery of cocaine, C17H21NO4, as the active component. Basic hydrolysis of cocaine leads to methanol, benzoic acid, and another compound called ecgonine, C9H15NO3. Oxidation of ecgonine with CrO3 yields a keto acid that readily loses CO2 on heating, giving tropinone. (a) What is a likely structure for the keto acid? (b) What is a likely structure for ecgonine, neglecting stereochemistry? (c) What is a likely structure for cocaine, neglecting stereochemistry?dedcue the major organic product from the following reations. be ablw to draw hydration halogenation hydrohalogenation, halohydrin formation, oxymercuratiom demercuration qnd hydroboration oxidation.Tunicates are marine animals that are called "sea squirts" because when they are taken out of water, they tend to contract and expel seawater. Lepadiformine is a cytotoxic agent (toxic to cells) isolated from a marine tunicate. During a recent synthesis of lepadiformine, the investigators observed the formation of an interesting by-product (3) while treating diol 1 with a reagent similar in function to PBr3 (J. Org. Chem. 2012, 77, 3390–3400):
- An inexperienced graduate student treated dec-5-ene with borane in THF, placed the flask in a refrigerator, and left for aparty. When he returned from the party, he discovered that the refrigerator was broken and that it had gotten quite warminside. Although all the THF had evaporated from the flask, he treated the residue with basic hydrogen peroxide. Tohis surprise, he recovered a fair yield of decan-1-ol. Use a mechanism to show how this reaction might have occurred.(Hint: The addition of BH3 is reversible.)Enamines formed from the cyclic secondary amine pyrrolidine are important intermediates in the synthesis of 1,5-diketones. (1st pic) On the structures provided below, draw arrows showing electron flow for the reaction mechanism for the acetic acid-catalyzed formation of an enamine from cyclohexanone and pyrrolidine. (2nd pic)Explain this result: Acetic acid (CH3COOH), labeled at its OH oxygen with the uncommon 18O isotope (shown in red), was treated with aqueousbase, and then the solution was acidified. Two products having the 18Olabel at different locations were formed.