What is the overall reaction under study? ki Step 1) NO + NO N2O2 k-1 Fast Step

Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter12: Kinetics
Section: Chapter Questions
Problem 83E: For each of the following reaction diagrams, estimate the activation energy (Ea) of the reaction:
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What is the overall reaction under study?
ki
Step 1) NO + NO N2O2
k-1
Fast Step
k2
Slow Step
Step 2) N202 + O2 2 NO2
Transcribed Image Text:What is the overall reaction under study? ki Step 1) NO + NO N2O2 k-1 Fast Step k2 Slow Step Step 2) N202 + O2 2 NO2
Identify the intermediate in the mechanism:
O NO2
O 02
O N202
N2O2
O NO
QUESTION 25
What is the rate law for the fast, elementary step in the mechanism?
O Rate = k2 [N2O2] [O2]
O Rate = k1 [No]
O Rate = k- 1 [N2O2]
O Ratefor
ki [NO] =k _ 1 N202]
Rate
%3D
rev, So
Transcribed Image Text:Identify the intermediate in the mechanism: O NO2 O 02 O N202 N2O2 O NO QUESTION 25 What is the rate law for the fast, elementary step in the mechanism? O Rate = k2 [N2O2] [O2] O Rate = k1 [No] O Rate = k- 1 [N2O2] O Ratefor ki [NO] =k _ 1 N202] Rate %3D rev, So
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