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A: Given,
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A: Atomic number of Mn = 25 Atomic number of Pt = 78
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Q: What coordination isomer can be written for [Co(en)3][Cr(ox)3]?
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A: As formula has 6 CN So, hexacyano Fe so, ferrate(III)
Q: 8
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Q: Provide the name of the coordination complex Na[CoCl4(NH3)2] b) Calculate the orbital multiplicity…
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Q: SAIC Ex7.1 Name and draw structures of the following complexes: a) [Ni(CO)4], b) [Ni(CN)4] , v)…
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Q: Which is the ligand in the coordination compound, [Co(NH3)6]C13? Co*3 O NH3 Co(NH3)6 cr
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Q: (a) There are essentially three bonding concepts used to describe the bonding in coordination…
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Q: 1. Sketch all isomers of the following. Indicate clearly each pair of enantiomers. Multidentate…
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Q: The complex (Fe(H,O)]* is paramagnetic. Is the H,0 ligand inducing a strong or weak field?
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A: The correct option is as follows:
Q: Identify each of the following coordination complexes as either diamagnetic or paramagnetic: (a)…
A:
Q: What are the electron configurations for an octahedral d7 complex with 1 weak-field and 2…
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Atomic Structure
The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.
Shape of the D Orbital
Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.
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- Show how to use the microanalysis data to determine the number of cod (C8H12) ligands per Pd. C, 33.65%; H, 4.24%; N, 0.00%; Pd, 37.27%.For [CoCl4]2-, Discuss the similarities/dissimilarities in the magnetic moment values with experimentally determined values of 5.0 and 4.4 µB for octahedral and tetrahedral complexes, respectively.F3C-M ligand is a pi acceptor/ pi donor or neither?
- The mating energy of the [CoF6]3- ion is 21000 cm−1, and ∆0 is 13000 cm−1. By calculating the KAKE of both the low and high spin states of the complex, determine in which state the compound is more stable.(a) What coordination geometries could [AuI4]− take and how might it differ from the [AuCl4]− ion? (b) Which of Ag(NO3) and Ag2S would be expected to be more effective at removing bromide, Br−, from solution? Explain your reasoning.Will methylamine (CH3NH2) be a monodentate or abidentate ligand? With which of its atoms will it bind to ametal ion?
- Ligand Field Stabilization Energy (LFSE) value (units of Δo) for: Zr3+ high-spin Fe3+ strong-field Ru2+ weak-field Cu3+ high-spin V+What point group is produced if an octahedral (Oh) complex is distorted by stretching two trans M-L bonds and compressing another two trans bonds? D4h D2d D2h C4vBy using the given 1) electronic absorption spectrum, 2) the Tanabo-Sugano diagram for d3 complex in octahedral ligand field and 3) the absorption/emission spectra, explain the following: a) Ligand field states (to support your explanation show the filling of the orbitals) b) Radiative transitions (to support your explanation refer to fluorescence, phosphorescence and Stokes’ shift)
- Determine the symmetry point groups of the mer- and fac- isomers of the complex [Re(CO)3(NCMe)3] and deduce the irreducible symmetry representations generated by the three stretching vibrations of the C triple bond to N ligands in each of the isomers. [Regard NCMe as a linear ligand.] Also for each isomer discussed, state with reasoning which vibrations are IR active, and which are Raman active and how many bands will be observable in IR and Raman spectra. How can you distinguish the two isomers using their vibrational spectra?The metal ion, M2+, formed a paramagnetic tetrahedral complex [MJ4]2+, having three unpaired electrons. Whereas, with the ligand monodentate anionic ligand A-, it forms the paramagnetic octahedral complex [MA6]4-, having the same number of unpaired electrons as that of for [MJ4]2+.Another octahedral, low-spin complex [MG3]2+, which has one unpaired electron. 1.Show the orbital diagrams for the determination of the hybridization of M2+ in the complexes [MA6]4- and [MG3]2+. Give the hybridization of M2+ in the complexes.The ligand thiocyanate (SCN-) is ambidentate. Which of the following metals will it most likely interact via the sulfur atom? Circle the letter for your choice and write a brief and clear justification fro your answer. a) Tl+ b) Pb2+ c) Cu2+ d) Fe3+ e) Zr4+