Which of the following compounds that has a stereoisomer that is a meso compound? DRAW THE DIAGRAM a) 1,3-dichlorocyclohexane DRAW THE DIAGRAM b) 1,2-dichlorocyclobutane DRAW THE DIAGRAM c) 1,4-dichlorocyclohexane DRAW THE DIAGRAM
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- Which stereoisomer has the lower overall energy? Draw the chair for the lowest energy conformation.Which of the four stereoisomers has the most stable conformation? Why?Which of the following structures represent the same stereoisomer? A. only 1 and 2 B. only 1 and 3 C. only 2 and 3 D. 1, 2 and 3 Please explain.
- Assign the absolute configuration to each chiral centers (signed with *).Shown below is Streptomycin, an antibiotic medication used to treat a number of bacterial infections, including tuberculosis, plague, and endocarditis. Neomycin B has broad-spectrum antibacterial activity. Circle and label as many functional groups in these molecules as you can. Label each chiral carbon in Streptomycin. How many total stereoisomers exist for Streptomycin? Label each chiral carbon in Neomycin B. How many total stereoisomers exist for Neomycin B?Draw all stereoisomers of the following compound and indicate which are enantiomers, disastereomers, or equal molecules.
- Ketones react with alcohols to yield products called acetals. Why does the all-cis isomer of 4-tert-butyl-1,3-cyclohexanediol react readily with acetone and an acid catalyst to form an acetal, but other stereoisomers do not react? In formulating your answer, draw the more stable chair conformations of all four stereoisomers and the product acetal for each one.Consider the molecule 1-bromo-2-methylbutane. C3 and C4 should be drawn as Et as in theexample. This group is called an ethyl group and can be considered a sphere about twice the sizeof a methyl group. Draw the following Newman projections sighting down the C1C2 bond... a. The lowest potential energy conformation. b. The highest potential energy staggered conformation.Stereoisomers share the same connectivity and differ only in the way their atoms are arranged in space. Draw the structure of a compound that is a stereoisomer of trans-1,2-dibromocyclobutane.(Note that the question asks for a different stereoisomer of the named compound and not the named compound itself.)Use the wedge/hash bond tools to indicate stereochemistry where it exists.In cases where there is more than one answer, just draw one.
- Draw the stereoisomer with all trans double bonds. Draw the Lewis structures with the formal charges minimized. Do not include formal charges or electron pairs. You do not need to draw hydrogen atoms that are connected to carbon atoms. TIP: For hydrogen atoms, you only need to draw H atoms that are not bonded to carbons (i.e. O-H and N-H). Draw the other optical isomer.Name the following compounds properly including stereochemistryFrom the isomers that you have drawn in using flying wedge notation before identify any enantiomeric pairs
