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- Explain why ethene does not react with HX ( X=Cl , Br or I) under normal conditions.Calculate the standard free energy of the following reactionsat 25°C, using standard free energies of formation. a. C2H4(g) + 3O2(g) ----> 2CO2(g) + 2H2O(l )b. CaCO3(s) + 2H+(aq) ----> Ca2+(aq) + H2O(l ) + CO2(g)A haloalkane reacts with a strong base to yield only one alkene product. Select the possible structures that can give this result from Figure 9. * A B C D
- For 10.29, the trans product (major product) and the cis product (third product) are displayed as possible E2 products. However, for 10.30, only the trans product (major product) is shown. How come the cis product is not needed?best condition for the reaction (1r,2s)-1 bromo-2methylcyclohexane->(s)3-methylcyclohex-1enePls ignore the highlighted part __________ is reduced in thefollowing reaction: Cr2O72- + 6S2O32-+ 14H+→ 2Cr3+ + 3S4O62- + 7H2O
- The methoxy group is reported as having σpara and σmeta values that differ in sign (σmeta =+0.12; σpara = –0.27). What specific experiments are performed to determine these s values?Explain why the σpara and σmeta values are of different sign and what those signs indicate.Rank the following according to INCREASING reactivity towards SN2: 1st (least reactive)? 2ND? 3RD? 4TH (most reactive)?1 example of reaction for each of the types of organic reactions: substitution, elimination, addition, and rearrangement. Show:a. the overall reaction (reactants --> products)b. the reaction mechanism (indicate intermediate product)c. indicate which is the reactive species or intermediate in the reaction (radical? electrophile? nucleophile?)d. overall description of the reaction eg., radical substitution or SR
- I’m currently trying to write a lab report for the synthesis of dimolybdenum tetraacetate [Mo2(O2CCH3)4] from the reaction of molybdenum hexacarbonyl, Mo(CO)6 in glacial acetic acid and acetic anhydride under a nitrogen atmosphere, involving the difficult formation of a quadruple bond and requires high heat and long reaction time (approximately 20 hours). But these are the question I’m stumped on: 1. Why need the reaction be done under nitrogen? We also added dichlorobenzene and hexanes during the reaction. 2. Explain the purpose of dichlorobenzene and hexanes. 3. Why does the reaction take 20 hrs?Predict the main product of the reaction in Figure 10. * A B C D The main product of the reaction cannot be predicted.Below is the equation for a nucleophilic substitution reaction and some experimental data. CH3CH2Br + CH3COO- ⇌ CH3CH2CO2CH3 + Br- Rate = k [CH3CH2Br][CH3COO-] Which mechanism would best fit the data?