Which of these ions cannotform both high- and low-spinoctahedral complexes: (a) Mn3+; (b) Nb3+; (c) Ru3+; (d) Ni2+?

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter19: Complex Ions
Section: Chapter Questions
Problem 41QAP: Give the number of unpaired electrons in octahedral complexes with strong-field ligands for (a) Rh3+...
icon
Related questions
Question

Which of these ions cannotform both high- and low-spinoctahedral complexes: (a) Mn3+; (b) Nb3+; (c) Ru3+; (d) Ni2+?

Expert Solution
Step 1

In an octahedral complex, the central atom is surrounded by six ligands. Depending upon the strength of the ligands, complexes can be classified into two types. They are strong field complex and weak field complex. Complexes formed by weak field ligands are called high-spin complexes whereas complexes formed by strong field ligands are called low spin complexes.  

Ions have the electron configuration d1, d2 and d3 forms high spin complexes, whereas d8 and d9 ions always form low spin complexes. 

Both low spin and high spin complexes are possible only for d4, d5, d6 and d7 ions.

Ions have electron d1, d2 and d3, d8 and d9 cannot form both high spin and low spin octahedral complexes.

 

steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Atomic Structure and Spectra
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
General Chemistry - Standalone book (MindTap Cour…
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
Chemistry: Principles and Practice
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning