Which one of the following statements is correct concerning the acetic acid in vinegar and neutralizing capacity of antacid experiments? O An antacid tablet is dissolved in H2O first then titrated with standardized NaOH solution. O One of the active ingredients in most commercial antacid tablets is Ca(OH)2. O The antacid tablet should be dissolved in an excess amount of HCI solution. O The titration flask should be rinsed with vinegar solution before titration with NaOH solution. O Starch can be used as an indicator in antacid experiment.

Which one of the following statements is correct concerning the acetic acid in vinegar and neutralizing capacity of antacid experiments? O An antacid tablet is dissolved in H2O first then titrated with standardized NaOH solution. O One of the active ingredients in most commercial antacid tablets is Ca(OH)2. O The antacid tablet should be dissolved in an excess amount of HCI solution. O The titration flask should be rinsed with vinegar solution before titration with NaOH solution. O Starch can be used as an indicator in antacid experiment.

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter14: Acid- Base Equilibria

Section: Chapter Questions

Problem 118CP: Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid w ith NaOH,...

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Given three acid-base indicatorsâ€”methyl orange (end point at pH 4), bromthymol blue (end point at pH 7), and phenolphthalein (end point at pH 9)â€”which would you select for the following acid-base titrations? (a) perchloric acid with an aqueous solution of ammonia (b) nitrous acid with lithium hydroxide (c) hydrobromic acid with strontium hydroxide (d) sodium fluoride with nitric acid
Explain why barium fluoride dissolves in dilute hydrochloric acid but is insoluble in water.
Malonic acid (HO2CCH2CO2H) is a diprotic acid. In the titration of malonic acid w ith NaOH, stoichiometric points occur at pH = 3.9 and 8.8. A 25.00-mL sample of malonic acid of unknown concentration is titrated with 0.0984 M NaOH, requiring 31.50 mL of the NaOH solution to reach the phenolphthalein end point. Calculate the concentration of the initial malonic acid solution. (Sec Exercise 113.)
. How is the strength of an acid related to the fact that a competition for protons exists in aqueous solution between water molecules and the anion of the acid?
Explain why an acid-base indicator changes color over a range of pH values rather than at a specific pH.
Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H) and the amine group (NHR) are protonated. However, as the pH of the solution increases (say, by adding base), the carboxylic acid proton is removed, usually at a pH between 2 and 3. In a middle range of pHs, therefore, the amine group is protonated, but the carboxylic acid group has lost the proton. (This is called a zwitterion.) At more basic pH values, the amine proton is dissociated. What is the pH of a 0.20 M solution of alanine hydrochloride, [NH3CHCH3CO2H]Cl?
Magnesium hydroxide and magnesium citrate function as mild laxatives when they reach the small intestine. Why do magnesium hydroxide and magnesium citrate, two very different substances, have the same effect in your small intestine. (Hint: The contents of the small intestine are basic.)
A diprotic acid, H2B(MM=126g/moL), is determined to be a hydrate, H2B xH2O. A 10.00-g sample of this hydrate is dissolved in enough water to make 150.0 mL of solution. Twenty-five milliliters of this solution requires 48.5 mL of 0.425 M NaOH to reach the equivalence point. What is x?
Consider all acid-base indicators discussed in this chapter. Which of these indicators would be suitable for the titration of each of these? (a) NaOH with HClO4 (b) acetic acid with KOH (c) NH3 solution with HBr (d) KOH with HNO3 Explain your choices.
Isocyanic acid (HNCO) can be prepared by heating sodium cyanate in the presence of solid oxalic acid according to the equation 2NaOCN(s)+H2C2O4(s)2HNCO(l)+Na2C2O4(s) Upon isolating pure HNCO(l), an aqueous solution of HNCO can be prepared by dissolving the liquid HNCO in water. What is the pH of a l00.-mL solution of HNCO prepared from the reaction of 10.0 g each of NaOCN and H2C2O4, assuming all of the HNCO produced is dissolved in solution? (Ka of HNCO = 1.2 l04.)
What is an acidbase indicator? Define the equivalence (stoichiometric) point and the end point of a titration. Why should you choose an indicator so that the two points coincide? Do the pH values of the two points have to be within 0.01 pH unit of each other? Explain.
What is the percentage of total acid expressed as acetic acid in a sample of vinegar if 4.0g of vinegar requires 29.5ml of 0.153N KOH for an endpoint with phenolphthalein indicator? (molar mass of acetic acid: HC2H3O2 = 60.05g/mol a. 3.995% b. 6.776% c. 8.650% d. 12.68%