Why does Hammett Equation only apply to meta and para substituted rings and not others? Explain

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter4: Polar Bonds, Polar Reactions
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Why does Hammett Equation only apply to meta and para substituted rings and not others? Explain

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