Why does one set of experiments give a positive r value, whereas the other set of experiments gives a negative r value?

Macroscale and Microscale Organic Experiments
7th Edition
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Kenneth L. Williamson, Katherine M. Masters
Chapter29: Friedel-crafts Alkylation Of Benzene And Dimethoxybenzene; Host-guest Chemistry
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Why does one set of experiments give a positive r value, whereas the other set of experiments gives a negative r value?

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